Brevetti Luca Castellani Nov 2015

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Thomson Innovation Patent Export, 2015-11-26 15:39:24 -0600 Record 1/36 US8475920B2 Cable with environmental stress cracking resistance Inventor: Pelizzoni, Andrea | Castellani, Luca | Peruzzotti, Franco | Puppi, Cristiano Abstract: Cable including at least one core comprising at least one transmissive element and at least one coating layer made of a coating material, wherein said coating material comprises: -at least one polyethylene; -at least one non-ionic surfactant having the following general formula (I): wherein: - Q is a p-functional group; -R is a linear or branched C1-C4 alkyl group, preferably a methyl group; -R1 is a hydrogen atom or a linear or branched C1-C6 alkyl group, preferably a hydrogen atom; -n is an integer from 2 to 5 inclusive, preferably 2; -x is an integer from 5 to 500 inclusive, preferably from 10 to 300 inclusive; -y is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; -z is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; -y+z is not lower than 2; -p is an integer from 1 to 4 inclusive, preferably 1 or 4; provided that, when the transmissive element is an electrical energy transmissive element, said at least one coating layer is an external sheathing layer. Preferably, said coating layer is an external sheathing layer having a protective function. Cable including at least one core comprising at least one transmissive element and at least one coating layer made of a coating material, wherein said coating material comprises: —at least one polyethylene; —at least one non-ionic surfactant having the following general formula (I): wherein: —Q is a p-functional group; —R is a linear or branched C 1 -C 4 alkyl group, preferably a methyl group; —R 1 is a hydrogen atom or a linear or branched C 1 -C 6 alkyl group, preferably a hydrogen atom; —n is an integer from 2 to 5 inclusive, preferably 2; —x is an integer from 5 to 500 inclusive, preferably from 10 to 300 inclusive; —y is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; —z is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; —y+z is not lower than 2; —p is an integer from 1 to 4 inclusive, preferably 1 or 4; provided that, when the transmissive element is an electrical energy transmissive element, said at least one coating layer is an external sheathing layer. Preferably, said coating layer is an external sheathing layer having a protective function. From corresponding WO2006000244A1 1

Transcript of Brevetti Luca Castellani Nov 2015

Page 1: Brevetti Luca Castellani Nov 2015

Thomson Innovation Patent Export, 2015-11-26 15:39:24 -0600

Record 1/36 US8475920B2 Cable with environmental stress cracking resistance

Inventor: Pelizzoni, Andrea | Castellani, Luca | Peruzzotti, Franco | Puppi, Cristiano

Abstract:

Cable including at least one core comprising at least one transmissive element and at least one

coating layer made of a coating material, wherein said coating material comprises: -at least one

polyethylene; -at least one non-ionic surfactant having the following general formula (I): wherein: -

Q is a p-functional group; -R is a linear or branched C1-C4 alkyl group, preferably a methyl group;

-R1 is a hydrogen atom or a linear or branched C1-C6 alkyl group, preferably a hydrogen atom; -n

is an integer from 2 to 5 inclusive, preferably 2; -x is an integer from 5 to 500 inclusive, preferably

from 10 to 300 inclusive; -y is an integer from 0 to 500 inclusive, preferably from 10 to 300

inclusive; -z is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; -y+z is not

lower than 2; -p is an integer from 1 to 4 inclusive, preferably 1 or 4; provided that, when the

transmissive element is an electrical energy transmissive element, said at least one coating layer

is an external sheathing layer. Preferably, said coating layer is an external sheathing layer having

a protective function.

Cable including at least one core comprising at least one transmissive element and at least one

coating layer made of a coating material, wherein said coating material comprises: —at least one

polyethylene; —at least one non-ionic surfactant having the following general formula (I): wherein:

—Q is a p-functional group; —R is a linear or branched C 1-C4 alkyl group, preferably a methyl

group; —R1 is a hydrogen atom or a linear or branched C1-C6 alkyl group, preferably a hydrogen

atom; —n is an integer from 2 to 5 inclusive, preferably 2; —x is an integer from 5 to 500 inclusive,

preferably from 10 to 300 inclusive; —y is an integer from 0 to 500 inclusive, preferably from 10 to

300 inclusive; —z is an integer from 0 to 500 inclusive, preferably from 10 to 300 inclusive; —y+z

is not lower than 2; —p is an integer from 1 to 4 inclusive, preferably 1 or 4; provided that, when

the transmissive element is an electrical energy transmissive element, said at least one coating

layer is an external sheathing layer. Preferably, said coating layer is an external sheathing layer

having a protective function.

From corresponding WO2006000244A1

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L'invention concerne un câble comprenant au moins un noyau comprenant un élément de

transmission et au moins une couche de revêtement en matériau de revêtement, ledit matériau

comprenant : au moins un tensioactif non ionique de formule (I), dans laquelle Q représente un

groupe fonctionnel p ; R représente un groupe alkyle C 1-C 4 linéaire ou ramifié, de préférence un

groupe méthyle ; R 1 représente un atome d'hydrogène ou un groupe alkyle C1-C6 linéaire ou

ramifié, de préférence un atome d'hydrogène ; n représente un nombre entier compris entre 2 et 5

compris, de préférence 2 ; x représente un nombre entier compris entre 5 et 500 compris, de

préférence compris entre 10 et 300 ; y représente un nombre entier compris entre 0 et 500, de

préférence entre 10 et 300 ; z représente un nombre entier compris entre 0 et 500, de préférence

entre 10 et 300 ; la somme y + z n'est pas inférieure à 2 ; p représente un nombre entier compris

entre 1 et 4, de préférence 1 ou 4. Lorsque l'élément de transmission est un élément de

transmission d'énergie électrique, la couche de revêtement est une couche de revêtement

externe. De préférence, ladite couche de revêtement est une couche de revêtement externe

présentant une fonction de protection.

From corresponding WO2006000244A1

L'invention concerne un câble comprenant au moins un noyau comprenant un élément de

transmission et au moins une couche de revêtement en matériau de revêtement, ledit matériau

comprenant : au moins un tensioactif non ionique de formule (I), dans laquelle Q représente un

groupe fonctionnel p ; R représente un groupe alkyle C<SUB>1</SUB>-C<SUB>4</SUB> linéaire

ou ramifié, de préférence un groupe méthyle ; R<SUB>1</SUB> représente un atome

d'hydrogène ou un groupe alkyle C<SUB>1</SUB>-C<SUB>6</SUB> linéaire ou ramifié, de

préférence un atome d'hydrogène ; n représente un nombre entier compris entre 2 et 5 compris,

de préférence 2 ; x représente un nombre entier compris entre 5 et 500 compris, de préférence

compris entre 10 et 300 ; y représente un nombre entier compris entre 0 et 500, de préférence

entre 10 et 300 ; z représente un nombre entier compris entre 0 et 500, de préférence entre 10 et

300 ; la somme y + z n'est pas inférieure à 2 ; p représente un nombre entier compris entre 1 et 4,

de préférence 1 ou 4. Lorsque l'élément de transmission est un élément de transmission d'énergie

électrique, la couche de revêtement est une couche de revêtement externe. De préférence, ladite

couche de revêtement est une couche de revêtement externe présentant une fonction de

protection.

Title: Cable with environmental stress cracking resistance

Title - DWPI: Electrical cable, e.g. for transmitting electrical energy has core comprising

transmissive component and coating layer made of coating material which comprises polyethylene

and nonionic surfactant

Publication Number: US8475920B2

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Priority Date: 2004-06-28

First Claim:

1. Cable including at least one core comprising at least one transmissive element and at least one

polymeric coating layer made of a polymeric coating material, wherein said polymeric coating

material comprises:

polyethylene present in the polymeric coating material in an amount of from 80% by weight to 99%

by weight with respect to the total weight of the polymeric coating material;

at least one non-ionic surfactant having the following general formula (I):

wherein:

Q is a p-functional group;

wherein R, R 1, n, x, y, z and p are independently selected for each variable as follows:

R 1 is a hydrogen atom or a linear or branched C1-C6 alkyl group;

R is a linear or branched C 1-C4 alkyl group;

n is an integer from 2 to 5 inclusive;

x is an integer from 5 to 500 inclusive;

y is an integer from 0 to 500 inclusive;

z is an integer from 0 to 500 inclusive;

y+z is not lower than 2;

p is an integer from 1 to 4 inclusive; and

wherein said at least one polymeric coating layer is a radially outermost polymeric sheathing layer

of the at least one core.

Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia SRL,Milan,IT | Pelizzoni Andrea,BovisioMasciago,IT | Castellani Luca,Milan,IT | Peruzzotti Franco,Legnano,IT | PuppiCristiano,Guanzate,IT

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Record 2/36 US8044110B2 Optical fiber with polymeric coating crosslinked in the presence ofboth radical and cationic photoinitiators Inventor: Castellani, Luca | Resmini, Emiliano | Rossiello, Luigia | Donetti, Raffaella Abstract: Optical fiber has a glass portion and at least one coating of crosslinked polymer materialsurrounding the glass portion, the coating being obtained by crosslinking a composition of (a) atleast one radically crosslinkable oligomer containing at least two reactive functional groups andhaving a number average molecular weight lower than about 1,000, preferably between about 400and about 900; (b) at least one cationically crosslinkable compound containing at least onereactive functional group; (c) at least one free radical photoinitiator; and (d) at least one cationicphotoinitiator. Preferably, the coating is a secondary coating or, in the case of a ribbon of opticalfibers, it is a common polymer coating known as a “common coating”. From corresponding WO2004106254A1 L'invention concerne une fibre optique (100) comprenant une partie en verre (101) et au moins unrevêtement (102, 103) en matière polymère réticulée entourant ladite partie en verre. Cerevêtement est obtenu par la réticulation d'une composition comprenant : (a) au moins unoligomère réticulable de manière radicalaire, contenant au moins deux groupes fonctionnelsréactifs et possédant un poids moléculaire moyen en nombre inférieur à environ 1 000, depréférence compris entre environ 400 et environ 900 ; (b) au moins un composé réticulable demanière cationique, contenant au moins un groupe fonctionnel réactif ; (c) au moins un photo-initiateur radicalaire ; (d) au moins un photo-initiateur cationique. Ledit revêtement est, depréférence, un revêtement secondaire ou, dans le cas d'un ruban de fibres optiques, unrevêtement polymère commun connu sous le nom de revêtement commun . From corresponding WO2004106254A1 L'invention concerne une fibre optique (100) comprenant une partie en verre (101) et au moins unrevêtement (102, 103) en matière polymère réticulée entourant ladite partie en verre. Cerevêtement est obtenu par la réticulation d'une composition comprenant : (a) au moins unoligomère réticulable de manière radicalaire, contenant au moins deux groupes fonctionnelsréactifs et possédant un poids moléculaire moyen en nombre inférieur à environ 1 000, depréférence compris entre environ 400 et environ 900 ; (b) au moins un composé réticulable demanière cationique, contenant au moins un groupe fonctionnel réactif ; (c) au moins un photo-initiateur radicalaire ; (d) au moins un photo-initiateur cationique. Ledit revêtement est, depréférence, un revêtement secondaire ou, dans le cas d'un ruban de fibres optiques, unrevêtement polymère commun connu sous le nom de </= REVêTEMENT COMMUN >/= . Title: Optical fiber with polymeric coating crosslinked in the presence of both radical and cationicphotoinitiators Title - DWPI: Optical fiber for use in cable, comprises glass portion and coating(s) of crosslinkedpolymer material crosslinked in presence of radical and cationic photoinitiators Publication Number: US8044110B2 Priority Date: 2003-05-29 First Claim: 1. A crosslinkable composition comprising:(a) at least one radically crosslinkable oligomer containing at least two reactive functional groupsand having a number average molecular weight lower than about 1,000;

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(b) at least one cationically crosslinkable compound containing at least one reactive functionalgroup,wherein the cationically crosslinkable compound is selected from vinyl ether terminated estercompounds having the following general formula: wherein: n is an integer from 1 to 4 inclusive;Y is a mono- di-, tri, or tetra-functional radical having a molecular weight of about 12 to about 500and is independently selected from the group consisting of alkyl, aryl, arylalkyl, and cycloalkylradicals;X is a divalent radical having a molecular weight of about 25 to about 500, each X beingindependently selected from the group consisting of alkylene and cycloalkylene radicals; andR 1 and R2, are monovalent radicals which are independently selected from the group consistingof hydrogen and alkyl groups having from 1 to 20 carbon atoms;(c) at least one free radical photoinitiator; and(d) at least one cationic photoinitiator. Front Page Drawing:

Assignee/Applicant: Prysmian Cavi e Sistemi Energia S.r.l.,Milan,IT

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Record 3/36 US7829164B2 Utility pole of thermoplastic composite material Inventor: Castellani, Luca | Testi, Stefano | Pavan, Massimiliano | Ponta, Thomas Abstract: A utility pole includes a thermoplastic composite material including: (a) at least one olefin polymer;and (b) at least one reinforcing fiber material embedded in the at least one olefin polymer, thethermoplastic composite material having a specific tensile strength higher than or equal to 15MPa/(gr/cm3), preferably 20 MPa/(gr/cm3) to 200 MPa/(gr/cm3), and more preferably 30MPa/(gr/cm3) to 150 MPa/(gr/cm3) and a specific tensile modulus higher than or equal to 2000MPa/(gr/cm3), preferably 2500 MPa/(gr/cm3) to 20000 MPa/(gr/cm3), and more preferably 3000MPa/(gr/cm3) to 15000 MPa/(gr/cm3). From corresponding WO2007042858A1 L'invention a pour objet un matelas (10) composé d'un substrat (20) et d'une enveloppe extérieurede confort déhoussable (30). Le substrat comprend un noyau structurel (21) et une enveloppefaisant barrière aux allergènes (22) entourant totalement le noyau. L'enveloppe extérieure deconfort possède une couche textile externe et une couche de bourre fixée mécaniquement à lacouche textile. L'enveloppe extérieure de confort est perméable à l'air et à la vapeur et présenteen particulier une perméabilité à l'air d'au moins 200 l/m<SUP>2</SUP>/s. Le substrat présenteune surface extérieure (25) comprenant une face supérieure (26), une face inférieure (26) et uneface latérale (28) s'étendant de la face supérieure à la face inférieure sur tout le pourtour dusubstrat. L'enveloppe extérieure de confort recouvre la surface extérieure de manière à ce que lacouche de bourre se trouve face à elle. L'enveloppe extérieure de confort s'étend sur une partielimitée de la surface extérieure du substrat du matelas de manière à recouvrir entièrement la facesupérieure de la surface extérieure et à découvrir au moins une partie de la face latérale et/ou dela face inférieure. From corresponding WO2007042858A1 L’invention a pour objet un matelas (10) composé d’un substrat (20) et d’une enveloppe extérieurede confort déhoussable (30). Le substrat comprend un noyau structurel (21) et une enveloppefaisant barrière aux allergènes (22) entourant totalement le noyau. L’enveloppe extérieure deconfort possède une couche textile externe et une couche de bourre fixée mécaniquement à lacouche textile. L’enveloppe extérieure de confort est perméable à l’air et à la vapeur et présenteen particulier une perméabilité à l’air d’au moins 200 l/m 2/s. Le substrat présente une surfaceextérieure (25) comprenant une face supérieure (26), une face inférieure (26) et une face latérale(28) s’étendant de la face supérieure à la face inférieure sur tout le pourtour du substrat.L’enveloppe extérieure de confort recouvre la surface extérieure de manière à ce que la couchede bourre se trouve face à elle. L’enveloppe extérieure de confort s’étend sur une partie limitée dela surface extérieure du substrat du matelas de manière à recouvrir entièrement la face supérieurede la surface extérieure et à découvrir au moins une partie de la face latérale et/ou de la faceinférieure. Title: Utility pole of thermoplastic composite material Title - DWPI: Telecommunication pole for supporting a telephone wire has thermoplasticcomposite material having a reinforcing material embedded to the olefin layer and a cross-sectionarea that decreases along the pole length Publication Number: US7829164B2 Priority Date: 2005-10-07

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First Claim: 1. A utility pole comprising a thermoplastic composite material comprising:(a) at least one olefin polymer; and(b) at least one reinforcing fiber material embedded in said at least one olefin polymer,said thermoplastic composite material having a specific tensile strength higher than or equal to 15MPa/(gr/cm 3) and a specific tensile modulus higher than or equal to 2000 MPa/(gr/cm3). Front Page Drawing:

Assignee/Applicant: Pirelli & C. S.p.A.,Milan,IT

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Record 4/36 US7764855B2 Optical fiber with cured polymeric coating Inventor: Roba, Giacomo Stefano | Terruzzi, Lidia | Fogliani, Sabrina | Castellani, Luca | Resmini,Emiliano | Donetti, Raffaella | Grassi, Lisa Abstract: An optical fiber having: a) a glass portion; and b) at least one protective coating layer disposed tosurround the glass portion, the protective coating layer having a modulus of elasticity valuebetween 40 C. and +60 C. between 5 MPa and 600 MPa, preferably not higher than 500 MPa,more preferably not higher than 450 MPa and much more preferably not higher than 300.Preferably the protective coating layer is a single protective coating layer which is disposed incontact with the glass portion. An optical fiber having: a) a glass portion; and b) at least one protective coating layer disposed tosurround the glass portion, the protective coating layer having a modulus of elasticity valuebetween 40° C. and +60° C. between 5 MPa and 600 MPa, preferably not higher than 500 MPa,more preferably not higher than 450 MPa and much more preferably not higher than 300.Preferably the protective coating layer is a single protective coating layer which is disposed incontact with the glass portion. From corresponding WO2004031091A1 L'invention concerne une fibre optique comprenant: a) une partie en verre; b) au moins unecouche de revêtement protecteur entourant la partie en verre; cette couche possédant une valeurde module d'élasticité, entre-40 °C et +60 °C, comprise entre 5 MPa et 600 MPa, plutôt inférieureà 500 MPa, ou encore mieux ne dépassant pas 450 MPa, mais de préférence inférieure à 300MPa. Cette couche de revêtement protecteur est constituée, de préférence, d'une couche uniqueen contact avec la partie en verre. From corresponding WO2004031091A1 L'invention concerne une fibre optique comprenant: a) une partie en verre; b) au moins unecouche de revêtement protecteur entourant la partie en verre; cette couche possédant une valeurde module d'élasticité, entre -40 DEG C et +60 DEG C, comprise entre 5 MPa et 600 MPa, plutôtinférieure à 500 MPa, ou encore mieux ne dépassant pas 450 MPa, mais de préférence inférieureà 300 MPa. Cette couche de revêtement protecteur est constituée, de préférence, d'une coucheunique en contact avec la partie en verre. Title: Optical fiber with cured polymeric coating Title - DWPI: Optical fiber comprises glass portion and protective coating layer(s) disposed tosurround glass portion and having specific modulus of elasticity Publication Number: US7764855B2 Priority Date: 2002-10-07 First Claim: 1. An optical fiber comprising:a glass portion; andat least one protective coating layer disposed to surround said glass portion;said at least one protective coating layer having a modulus of elasticity value between 5 MPa and600 MPa over the range between 40° C. and +60° C. Front Page Drawing:

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Assignee/Applicant: Prysmian Cavi e Sistemi Energia S.R.L.,Milan,IT

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Record 5/36 BRPI0318517B1 cabo para transportar ou distribuir energia elétrica de média/altatensão, e, processo para produzir o mesmo. Inventor: Castellani, Luca | Pelizzoni, Andrea | Peruzzotti, Franco | Albizzati, Enrico Abstract: Title: cabo para transportar ou distribuir energia elétrica de média/alta tensão, e, processo paraproduzir o mesmo. Title - DWPI: Cable for transmitting both electrical energy and optical signals, has core havingtransmissive element(s) and coating layer made from coating material comprising firstpolyethylene obtained from waste material, and second polyethylene Publication Number: BRPI0318517B1 Priority Date: 2003-09-30 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 6/36 US7652101B2 Thermoplastic material comprising a vulcanized rubber in asubdivided form Inventor: Tirelli, Diego | Galbusera, Michele | Castellani, Luca | Peruzzotti, Franco | Albizzati,Enrico Abstract: A thermoplastic material has a) from 5% weight to 95% by weight, preferably from 10% by weightto 60% by weight, of vulcanized rubber in a subdivided form; b) from 5% by weight to 95% byweight, preferably from 40% by weight to 90% by weight, of at least one heterophase copolymerhaving a thermoplastic phase made from a propylene homopolymer or copolymer and anelastomeric phase made from a copolymer of ethylene with an alpha-olefin, preferably withpropylene; c) from 0% by weight to 90% by weight, preferably from 0% by weight to 50% byweight, of at least one alpha-olefin homopolymer or copolymer different from b); the amounts of a),b) and c) being expressed with respect to the total weight of a)+b)+c). The thermoplastic materialshows improved mechanical properties, in particular, improved elongation at break. A thermoplastic material has a) from 5% weight to 95% by weight, preferably from 10% by weightto 60% by weight, of vulcanized rubber in a subdivided form; b) from 5% by weight to 95% byweight, preferably from 40% by weight to 90% by weight, of at least one heterophase copolymerhaving a thermoplastic phase made from a propylene homopolymer or copolymer and anelastomeric phase made from a copolymer of ethylene with an -olefin, preferably with propylene;c) from 0% by weight to 90% by weight, preferably from 0% by weight to 50% by weight, of at leastone -olefin homopolymer or copolymer different from b); the amounts of a), b) and c) beingexpressed with respect to the total weight of a)+b)+c). The thermoplastic material shows improvedmechanical properties, in particular, improved elongation at break. From corresponding WO2004087803A1 La présente invention a trait à un matériau thermoplastique comportant : a) de 5 % en poids à 95% en poids, de préférence de 10 % en poids à 60 % en poids, de caoutchouc vulcanisé en uneforme subdivisée ; b) de 5 % en poids à 95 % en poids, de préférence de 40 % en poids à 90 %en poids, d'au moins un homopolymère ou copolymère de propylène et une phase à based'élastomère préparée à partir d'un copolymère d' éthylène avec une -oléfine, de préférence avecdu propylène ; c) de 0 % en poids à 90 % en poids, de préférence de 0 % en poids à 50 % enpoids, d'au moins un homopolymère ou copolymère d'-oléfine différente de b) ; les quantités de a),b), c) étant exprimées par rapport au poids total de a) + b) + c). Ledit matériau thermoplastiqueprésente des propriétés mécaniques améliorées, notamment, un allongement à la ruptureamélioré. From corresponding WO2004087803A1 La présente invention a trait à un matériau thermoplastique comportant : a) de 5 % en poids à 95% en poids, de préférence de 10 % en poids à 60 % en poids, de caoutchouc vulcanisé en uneforme subdivisée ; b) de 5 % en poids à 95 % en poids, de préférence de 40 % en poids à 90 %en poids, d'au moins un homopolymère ou copolymère de propylène et une phase à based'élastomère préparée à partir d'un copolymère d'éthylène avec une alpha -oléfine, de préférenceavec du propylène ; c) de 0 % en poids à 90 % en poids, de préférence de 0 % en poids à 50 %en poids, d'au moins un homopolymère ou copolymère d' alpha -oléfine différente de b) ; lesquantités de a), b), c) étant exprimées par rapport au poids total de a) + b) + c). Ledit matériau

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thermoplastique présente des propriétés mécaniques améliorées, notamment, un allongement à larupture amélioré. Title: Thermoplastic material comprising a vulcanized rubber in a subdivided form Title - DWPI: Thermoplastic material for use in manufactured product, e.g. industrial, sport, orsafety surfaces, comprises vulcanized rubber, heterophase copolymer(s) having thermoplastic andelastomeric phases, and alpha-olefin homopolymer or copolymer Publication Number: US7652101B2 Priority Date: 2003-03-31 First Claim: 1. A thermoplastic material comprising:(a) 5% by weight to 95% by weight of a vulcanized rubber in a subdivided form;(b) 5% by weight to 95% by weight of at least one heterophase copolymer comprising athermoplastic phase made from a propylene homopolymer or copolymer and an elastomericphase made from a copolymer of ethylene with an -olefin; and(c) 0% by weight to 90% by weight of at least one -olefin homopolymer or copolymer different from(b);the amounts of (a), (b) and (c) being expressed with respect to the total weight of (a)+(b)+(c). Front Page Drawing:

Assignee/Applicant: Pirelli & C. S.p.A.,Milan,IT

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Record 7/36 ES2345037T3 CABLE DE FIBRA OPTICA CON COMPONENTE POLIMERICO DEDIMENSIONES ESTABLES. Inventor: CASTELLANI LUCA | MARITANO MAURO | BRANDI GIOVANNI Abstract: Cable de fibra óptica que comprende un componente de cable adecuado para recibir y alojar almenos una fibra óptica, en el que el componente de cable está hecho de un material poliméricoque comprende un copolímero aleatorio cristalino de propileno con al menos una -olefina C4-C8 yen el que el copolímero contiene de aproximadamente 4% a aproximadamente 10% en peso de la-olefina C4-C8, con respecto al peso total del copolímero. Title: CABLE DE FIBRA OPTICA CON COMPONENTE POLIMERICO DE DIMENSIONESESTABLES. Title - DWPI: Optical fiber cable used in terrestrial and under sea environment, comprises cablecomponent made of polymeric material comprising crystalline random copolymer of propylene withalpha-olefin(s) Publication Number: ES2345037T3 Priority Date: 2001-05-30 | 2001-06-01 First Claim: Front Page Drawing:

Assignee/Applicant: PRYSMIAN SPA

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Record 8/36 US7162130B2 Optical fiber with thermoplastic material based coating Inventor: Castellani, Luca | Brandi, Giovanni | Maritano, Mauro | Peruzzotti, Franco | Roba,Giacomo Stefano | Fogliani, Sabrina | Terruzzi, Lidia Abstract: Optical fiber having a glass portion; at least one protective coating of thermoplastic material havingat least one thermoplastic elastomer; the thermoplastic material having the followingcharacteristics: a modulus of elasticity value at +25° C. lower than 150 MPa, preferably at least 10Mpa, more preferably higher than 20 Mpa, and a Vicat point higher than 85° C., preferably higherthan 120° C., more preferably lower than 350° C. Preferably, the coating is a single protectivecoating directly positioned onto the glass portion. Title: Optical fiber with thermoplastic material based coating Title - DWPI: Optical fiber useful in production of optical cables, comprises protective coating(s) ofthermoplastic material comprising thermoplastic elastomer(s), where thermoplastic material hasspecific modulus of elasticity, and vicat point Publication Number: US7162130B2 Priority Date: 2002-10-23 First Claim: 1. An optical fiber comprising:a glass portion; at least one protective coating of thermoplastic material comprising at least one thermoplasticelastomer; said thermoplastic material having the following characteristics: a modulus of elasticity value at +25° C. lower than 150 MPa; and a Vicat point higher than 85° C. Front Page Drawing:

Assignee/Applicant: Prysmian Cavi e Sistemi Energia S.r.l.,Milan,IT

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Record 9/36 BRPI0206821B1 fibra óptica, composição reticulável, e, método para a aplicação deum revestimento baseado em poliolefina epoxidada em uma fibra óptica. Inventor: Castellani, Luca | Rossiello, Luigia | Pelizzoni, Andrea | Donetti, Raffaella | Terruzzi,Lidia | Maritano, Mauro Abstract: Title: fibra óptica, composição reticulável, e, método para a aplicação de um revestimentobaseado em poliolefina epoxidada em uma fibra óptica. Title - DWPI: Optical fiber, comprises hydrogenated polydiene oligomer including reactivefunctional groups capable of reacting with epoxide groups at end of epoxidized polydiene oligomer Publication Number: BRPI0206821B1 Priority Date: 2001-12-06 | 2002-02-18 | 2002-11-28 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 10/36 BRPI0016575B1 cabo elétrico, e, método para bloquear o fluxo longitudinal deágua. Inventor: Belli, Sergio | Bareggi, Alberto | Veggetti, Paolo | Castellani, Luca | Pozzati, Giovanni |Balconi, Luca Abstract: Title: cabo elétrico, e, método para bloquear o fluxo longitudinal de água. Title - DWPI: Electric cable, for transmitting power at preset voltage, comprises water swellablelayer made of expanded material embedded with water swellable material, is positioned radiallyexternal to metallic screen Publication Number: BRPI0016575B1 Priority Date: 1999-12-20 | 2000-12-15 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 11/36 BRPI0116824B1 cabo de telecomunicações Inventor: Castellani, Luca | Brandi, Giovanni | Pavan, Massimiliano Abstract: Title: cabo de telecomunicações Title - DWPI: Telecommunication cable, includes tubular element of polymeric material made frompolymeric composition comprising heterophasic olefin copolymer Publication Number: BRPI0116824B1 Priority Date: 2001-11-28 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 12/36 BRPI0112004B1 cabo para transporte ou distribuição de energia elétrica em médiae alta voltagens, e, composição polimérica usada para confecção do cabo. Inventor: Castellani, Luca | Martinotto, Luca | Scelza, Cristiana | Albizzati, Enrico Abstract: Title: cabo para transporte ou distribuição de energia elétrica em média e alta voltagens, e,composição polimérica usada para confecção do cabo. Title - DWPI: Cable for transporting or distributing medium or high voltage energy, compriseselectrical conductor(s) and covering layer(s) based on thermoplastic polymer material mixed withdielectric liquid Publication Number: BRPI0112004B1 Priority Date: 2000-06-28 | 2001-06-15 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 13/36 US6861143B2 Cable with recyclable covering Inventor: Castellani, Luca | Scelza, Cristiana | Dell'Anna, Gaia | Albizzati, Enrico Abstract: A cable includes at least one conductor and at least one covering layer. The at least one coveringlayer includes a thermoplastic polymer material. The polymer material includes a propylenehomopolymer or a copolymer of propylene with an olefin comonomer. The olefin comonomer isethylene, one or more -olefins other than propylene, or ethylene and one or more -olefins otherthan propylene. The homopolymer or copolymer has a melting point between 140° C. and 165° C.,a melting enthalpy between 30 J/g and 80 J/g, a boiling diethyl ether soluble fraction less than orequal to 12 wt % and melting enthalpy less than or equal to 4 J/g, a boiling n-heptane solublefraction between 15 wt % and 60 wt % and melting enthalpy between 10 J/g and 40 J/g, and aboiling n-heptane insoluble fraction between 40 wt % and 8 wt % and melting enthalpy greaterthan or equal to 45 J/g. A cable includes at least one conductor and at least one covering layer. The at least one coveringlayer includes a thermoplastic polymer material. The polymer material includes a propylenehomopolymer or a copolymer of propylene with an olefin comonomer. The olefin comonomer isethylene, one or more alpha-olefins other than propylene, or ethylene and one or more alpha-olefins other than propylene. The homopolymer or copolymer has a melting point between 140° C.and 165° C., a melting enthalpy between 30 J/g and 80 J/g, a boiling diethyl ether soluble fractionless than or equal to 12 wt % and melting enthalpy less than or equal to 4 J/g, a boiling n-heptanesoluble fraction between 15 wt % and 60 wt % and melting enthalpy between 10 J/g and 40 J/g,and a boiling n-heptane insoluble fraction between 40 wt % and 8 wt % and melting enthalpygreater than or equal to 45 J/g. Title: Cable with recyclable covering Title - DWPI: Cable, for medium and high voltage electricity cables, comprises recyclable coveringof propylene homopolymer or copolymer with specified melting and solvent solubility properties Publication Number: US6861143B2 Priority Date: 1999-11-17 | 1999-11-19 | 2000-11-13 First Claim: 1. A cable, comprising:at least one conductor; and at least one covering layer; wherein the at least one covering layer comprises a thermoplastic polymer material, wherein the thermoplastic polymer material comprises: a propylene homopolymer; or a copolymer of propylene with an olefin comonomer; wherein the olefin comonomer is ethylene, one or more -olefins other than propylene, or ethyleneand one or more -olefins other than propylene, wherein the propylene homopolymer or copolymer of propylene has: a melting point between 140° C. and 165° C.; a melting enthalpy between 30 J/g and 80 J/g; a boiling diethyl ether soluble fraction less than or equal to 12 wt %, wherein the boiling diethylether soluble fraction has a melting enthalpy less than or equal to 4 J/g; a boiling n-heptane soluble fraction between 15 wt % and 60 wt %, wherein the boiling n-heptanesoluble fraction has a melting enthalpy between 10 J/g and 40 J/g; and

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a boiling n-heptane insoluble fraction between 40 wt % and 85 wt %, wherein the boiling n-heptane insoluble fraction has a melting enthalpy greater than or equal to 45 J/g. Front Page Drawing:

Assignee/Applicant: Pirelli Cavi e Sistemi S.p.A.,Milan,IT

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Record 14/36 US6828505B1 Method and electrical apparatus comprising a water tree resistantinsulating composition Inventor: Peruzzotti, Franco | Castellani, Luca | Dacal, Luis José | Garcia, Valeria Abstract: The present invention is an improved electric insulation composition of a polymer and an additivethat reduces water treeing due to electrical aging in water. The polymer additive is ahydrophobic/hydrophilic material with good compatibility with the polymer. The present invention isalso a method of preventing electrical breakdown due to the formation of water trees by formingelectrical cables with the insulation containing the disclosed anti-treeing additives. Title: Method and electrical apparatus comprising a water tree resistant insulating composition Title - DWPI: Electrical apparatus for electrical cable used in the presence of water comprises anelectrical insulating composition containing a polyolefin comprising an effective amount of a water-tree resistant additive Publication Number: US6828505B1 Priority Date: 1996-06-21 | 1996-09-24 First Claim: 1. An electrical apparatus comprising:a polymeric electrically insulating composition comprising a polyolefin as a major component andan effective amount of a water-tree resistant additive dispersed into said electrically insulatingcomposition, said additive having: a hydrophilic portion, causing a water absorption in said polymeric insulation layer within aselected absorption range, a compatible portion with said polyolefin, causing an additive loss by contact with water lower thana selected loss value, said hydrophilic portion having a mobility suitable to allow the hydrophilic portion of the additive toeffectively reach and link water molecules diffusing in said electrically insulating composition, andwherein said electrically insulating composition comprises no carbon black, such that saidelectrical apparatus has a residual electrical breakdown strength greater than about 35 kV/mmupon 120 days accelerated water treeing test according to AEIC CS 5-94. Front Page Drawing:

Assignee/Applicant: Pirelli Cavi S.p.A.,Milan,IT

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Record 15/36 HU229633B1 CABLE WITH RECYCLABLE COVERING Inventor: CASTELLANI LUCA | DELL ANNA GAIA | SCELZA CRISTIANA | ALBIZZATI ENRICO Abstract: Title: CABLE WITH RECYCLABLE COVERING Title - DWPI: Cable for transporting and distributing medium or high voltage electrical energy, hascovering made of thermoplastic polymer comprising homo- or copolymer of propylene with olefincomonomer and dielectric liquid Publication Number: HU229633B1 Priority Date: 2000-09-28 | 2000-10-02 | 2001-08-22 First Claim: Front Page Drawing:

Assignee/Applicant: PRYSMIAN CAVI E SISTEMI EN SRL

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Record 16/36 BR9810782B CABO COM PROPRIEDADES AUTO-EXTINGUÍVEIS,COMPOSIÇÃO RETARDANTE DE CHAMA, E, PROCESSO PARA FABRICAR DITO CABO. Inventor: GRIZANTE REDONDO EDUARDO | PERUZZOTTI FRANCO | TIRELLI DIEGO |ZAOPO ANTONIO | ALBIZZATI ENRICO | CASTELLANI LUCA Abstract: Title: CABO COM PROPRIEDADES AUTO-EXTINGUÍVEIS, COMPOSIÇÃO RETARDANTE DECHAMA, E, PROCESSO PARA FABRICAR DITO CABO. Title - DWPI: Publication Number: BR9810782B Priority Date: 1997-07-23 | 1997-07-23 | 1997-12-01 | 1998-07-10 First Claim: Front Page Drawing:

Assignee/Applicant: PIRELLEI CAVI E SISTEMI SPA

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Record 17/36 BRPI9916659B1 cabo compreendendo um condutor e pelo menos uma camada derevestimento com base em um material de polìmero não reticulado. Inventor: Castellani, Luca | Scelza, Cristiana | Albizzati, Enrico Abstract: Title: cabo compreendendo um condutor e pelo menos uma camada de revestimento com baseem um material de polìmero não reticulado. Title - DWPI: Medium-voltage or high-voltage electrical cable for power transmission has arecyclable coating based on a non-crosslinked polymer material Publication Number: BRPI9916659B1 Priority Date: 1998-12-30 | 1999-12-21 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 18/36 BRPI0001533B1 cabo de auto-extinção e baixo nìvel de produção de fumaça, e,composição retardante de chama. Inventor: Castellani, Luca | Tireli, Diego | Peruzotti, Franco | Albizzati, Enrico Abstract: Title: cabo de auto-extinção e baixo nìvel de produção de fumaça, e, composição retardante dechama. Title - DWPI: Cable for telecommunication, has flame retardant coating layer having heterophasecopolymer having elastomeric phase of ethylene copolymer and thermoplastic phase of propylene,and flame retardant inorganic filler Publication Number: BRPI0001533B1 Priority Date: 1999-04-03 First Claim: Front Page Drawing:

Assignee/Applicant: Prysmian Cavi E Sistemi Energia S.r.l.,IT

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Record 19/36 ES2214517T3 PROCEDIMIENTO DE FABRICACION DE CABLESMINIATURIZADOS, MULTIPOLARES Y RESISTENTES A LA PROPAGACION DE LLAMAS QUETIENEN UNA EMISION REDUCIDA DE GASES TOXICOS Y NO TOXICOS, Y CABLESOBTENIDOS POR DICHO PROCEDIMIENTO. Inventor: CASTELLANI LUCA | DE RAI LUCA | VOLPE PASQUALE Abstract: EL PROCESO DE LA INVENCION REALIZA CABLES MULTIPOLARES MINIATURIZADOS QUECOMPRENDE LAS ETAPAS DE COMBINAR JUNTOS UNA PLURALIDAD DE CONDUCTORESAISLADOS INDIVIDUALMENTE, QUE INSERTAN UN RELLENO EN UN ESTADO PASTOSO YQUE CONTIENE RELLENOS DE MINERALES DENTRO DE LOS ESPACIOS QUE EXISTENENTRE LOS CONDUCTORES, EN PARTE ENDURECE EL RELLENO Y QUE DEPOSITA LASCOMPONENTES DEL CABLE, EN PARTICULAR LA FUNDA, ALREDEDOR EL MONTAJERELLENO DE CONDUCTORES, QUE ADJUDICAN EL RELLENO SE CONVIERTECOMPLETAMENTE DURO DENTRO DEL CABLE PRODUCIDO. Title: PROCEDIMIENTO DE FABRICACION DE CABLES MINIATURIZADOS, MULTIPOLARESY RESISTENTES A LA PROPAGACION DE LLAMAS QUE TIENEN UNA EMISION REDUCIDADE GASES TOXICOS Y NO TOXICOS, Y CABLES OBTENIDOS POR DICHOPROCEDIMIENTO. Title - DWPI: Mfr. of miniaturised multipolar cables having reduced toxic gas emission bycombining insulating covered electrical conductors and filling gaps between conductors withpolymer contg. mineral fillers Publication Number: ES2214517T3 Priority Date: 1995-10-11 First Claim: Front Page Drawing:

Assignee/Applicant: PIRELLI & C SPA

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Record 20/36 US6110592A Method for the preparation of a polymeric mixture for cable insulatorsand coatings, polymeric mixture thus produced and cables containing it Inventor: Grizante, Redondo Eduardo | Zaopo, Antonio | Castellani, Luca Abstract: Method for the preparation of a polymeric mixture for cable insulators and coatings and sheathsfor optic fiber cables; polymeric mixture thus produced and the cables containing it.<P><P>Themethod is characterized in that one completely mixes, up to the obtainment of a homogeneouscomposition, (i) from 50 to 80 parts (w/w) of a first thermoplastic polymer which is amorphous,highly resistant to flames and combustion, and consists of an aromatic polyester of isophthalic andterephthalic acid with bisphenol A, and (ii) from 20 to 50 parts (w/w) of at least a secondthermoplastic polymer consisting of an elastomeric polyether-ester block copolymer, having aShore D hardness greater than 50 and a Vicat softening point greater than 170° C., for a mixingtime less than 10 minutes. Method for the preparation of a polymeric mixture for cable insulators and coatings and sheathsfor optic fiber cables; polymeric mixture thus produced and the cables containing it. The method ischaracterized in that one completely mixes, up to the obtainment of a homogeneous composition,(i) from 50 to 80 parts (w/w) of a first thermoplastic polymer which is amorphous, highly resistant toflames and combustion, and consists of an aromatic polyester of isophthalic and terephthalic acidwith bisphenol A, and (ii) from 20 to 50 parts (w/w) of at least a second thermoplastic polymerconsisting of an elastomeric polyether-ester block copolymer, having a Shore D hardness greaterthan 50 and a Vicat softening point greater than 170 DEG C., for a mixing time less than 10minutes. Title: Method for the preparation of a polymeric mixture for cable insulators and coatings,polymeric mixture thus produced and cables containing it Title - DWPI: Polymer mixt. for cable coatings comprises aromatic polyester of bisphenol andisophthalic and terephthalic acids and thermoplastic elastomeric polyether ester! block copolymer Publication Number: US6110592A Priority Date: 1991-10-31 First Claim: 1. A cable coating formed by a polymeric mixture comprising from 50 to 80 parts (w/w) of a firstthermoplastic polymer which is amorphous, highly resistant to flames and combustion, andconsists of an aromatic polyester of isophthalic and terephthalic acid with bisphenol A, and from20 to 50 parts (w/w) of at least a second thermoplastic polymer consisting of an elastomericpolyether-ester block copolymer, having a Shore D hardness greater than 50 and a Vicat softeningpoint greater than 170° C., said mixture having an ultimate elongation not lower than 50% whenthe amount of the second polymer is the lowest one and a higher ultimate elongation as theamount of said second polymer increases wherein said first thermoplastic polymer and said atleast a second thermoplastic polymer are not chemically combined and said thermoplasticpolymers are not cross-linked with themselves. Front Page Drawing:

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Assignee/Applicant: Pirelli Cavi SA.,Milan,IT

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Record 21/36 DE69710654T2 Selbstverlöschendes Kabel mit niedriger Abgabe von giftigem undkorrosivem Rauch und Gas Inventor: Castellani, Luca Abstract: Title: Selbstverlöschendes Kabel mit niedriger Abgabe von giftigem und korrosivem Rauch undGas Title - DWPI: Publication Number: DE69710654T2 Priority Date: 1996-07-30 First Claim: Front Page Drawing:

Assignee/Applicant: Pirelli Cavi e Sistemi S.p.A.

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Record 22/36 ES2133661T3 CABLE AUTO EXTINGUIBLE QUE LIBERA BAJAS CANTIDADESDE HUMOS Y GASES TOXICOS Y CORROSIVOS, Y PROCEDIMIENTO DE PREPARACION. Inventor: CASTELLANI LUCA Abstract: UN CABLE, AUTOEXTINGUIBLE Y QUE LIBERA BAJAS CANTIDADES DE HUMOS Y GASESTOXICOS Y CORROSIVOS PARA APLICACIONES OPTICAS O ELECTRICAS COMPRENDEUN REVESTIMIENTO (3) QUE INCLUYE UNA CAPA EXTERIOR (5) QUE CONSTA DE UNAMEZCLA POLIMERICA QUE INCLUYE ENTRE 50 Y 80 PARTES (POR PESO) DE UNPOLIESTER AROMATICO DE LOS ACIDOS ISOFTALICOS Y TEREFTALICOS, CONBISFENOL A Y ENTRE 20 Y 50 PARTES (POR PESO) DE UN COPOLIMERO DEELASTOMERO DE BLOQUE DE POLIETER-POLIESTER QUE TIENE UNA DUREZA DE"SHORE" D MAYOR DE 50 Y UN PUNTO DE REBLANDECIMIENTO "VICAT" MAYOR DE 170(GRADOS) C, ASI COMO UNA CAPA INTERNA COAXIAL (4) QUE COMPRENDE UNELASTOMERO TERMOPLASTICO DE POLIESTER QUE INCLUYE UNA CANTIDAD DEGRUPOS AROMATICOS TAL QUE SU DUREZA "SHORE" D ES IGUAL A AL MENOS 45 Y TALQUE LAS FUERZAS DE CORTE DE DESLAMINACION NECESARIAS PARA SEPARAR LASCAPAS (4, 5) ES IGUAL A AL MENOS 2000 GRS DESPUES DE SU ENVEJECIMIENTO ENACEITE ASTM NUMERO 3 DURANTE 2 HORAS A 100 (GRADOS) C. Title: CABLE AUTO EXTINGUIBLE QUE LIBERA BAJAS CANTIDADES DE HUMOS Y GASESTOXICOS Y CORROSIVOS, Y PROCEDIMIENTO DE PREPARACION. Title - DWPI: Cable with 2-layer self-extinguishing outer coating the inner layer comprising athermoplastic polyester elastomer including aromatic gps., providing good adhesion to the outerlayer Publication Number: ES2133661T3 Priority Date: 1994-12-23 First Claim: Front Page Drawing:

Assignee/Applicant: PIRELLI CAVI E SISTEMI SPA

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Record 23/36 DE69305781T2 Hochtemperaturkabel Inventor: Grizante Redondo, Eduardo | Castellani, Luca | Zaopo, Antonio Abstract: Title: Hochtemperaturkabel Title - DWPI: Publication Number: DE69305781T2 Priority Date: 1992-05-08 First Claim: Front Page Drawing:

Assignee/Applicant: Pirelli Cavi S.p.A.

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Record 24/36 US20070292644A1 Process for Producing a Composite Material Inventor: Carrus, Antonio | Cipriani, Chlara | Grassi, Lisa | Testi, Stefano | Castellani, Luca Abstract: A process for producing a composite material includes the following steps: (a) melting at least onepolyester having an inherent viscosity higher than or equal to 0.5 dl/g, preferably 0.6 dl/g to 1.2dg/l; (b) cooling said polyester so as to obtain a polyester having a crystallinity lower than 30%,preferably 1% to 20%; and (c) mixing at least one layered clay material with the polyester obtainedin step (b) so as to obtain the composite material. The composite material is particularly useful formanufacturing food or beverage containers, in particular bottles. Title: Process for Producing a Composite Material Title - DWPI: Producing a composite material, useful in food or beverage containers, comprisesmelting a polyester; cooling the polyester to obtain an another polyester; and mixing a layered claymaterial to the polyester obtained Publication Number: US20070292644A1 Priority Date: 2004-11-23 First Claim: 1-48. (canceled) Front Page Drawing:

Assignee/Applicant:

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Record 25/36 EP2935447A1 TYRE FOR VEHICLE WHEELS | REIFEN FÜR FAHRZEUGRÄDER| PNEUMATIQUE DESTINÉ À DES ROUES DE VÉHICULE Inventor: HANEL, Thomas | CASTELLANI, Luca | ORLANDI, Marco | FRIGERIO, Paola | ZOIA,Luca Abstract: From corresponding WO2014097108A1 The present invention relates to a tyre for vehicle wheels comprising at least one structuralelement comprising a cross-linked elastomeric material obtained by crosslinking a crosslinkableelastomeric composition comprising (a) at least one dienic elastomeric polymer; (b) at least onecarbon black reinforcing filler; and (c) at least one functionalized lignin selected from the groupconsisting of esterified lignin and etherified and esterified lignin. From corresponding WO2014097108A1 La présente invention concerne un pneumatique destiné à des roues de véhicule comprenant aumoins un élément structural comprenant un matériau élastomère réticulé obtenu par réticulationd'une composition élastomère réticulable comprenant (a) au moins un polymère élastomère detype diène ; (b) au moins une charge de renforcement de type noir de carbone ; et (c) au moinsune lignine fonctionnalisée choisie dans le groupe constitué par la lignine estérifiée et la lignineéthérifiée et estérifiée. Title: TYRE FOR VEHICLE WHEELS | REIFEN FÜR FAHRZEUGRÄDER | PNEUMATIQUEDESTINÉ À DES ROUES DE VÉHICULE Title - DWPI: Tire for vehicle wheels comprises structural element having cross-linked elastomericmaterial prepared by crosslinking a crosslinkable elastomeric composition comprising dienicelastomeric polymer/reinforcing filler/functionalized lignin Publication Number: EP2935447A1 Priority Date: 2012-12-18 | 2013-03-19 | 2013-12-16 First Claim: From corresponding WO2014097108A1 1. (a) at least one dienic elastomeric polymer;(b) at least one carbon black reinforcing filler; and (c) at least one functionalized lignin, wherein said functionalized lignin is selected from the group consisting of esterified lignin andetherified and esterified lignin. Tyre for vehicle wheels according to claim 1 , wherein said tyre for vehicle wheels comprises: a carcass structure comprising at least one carcass layer having opposed side edges associatedwith relative annular reinforcing structures; a belt structure applied in a radially outer position with respect to said carcass structure; a tread band applied in a radially outer position with respect to said carcass structure; and a pair of sidewalls laterally applied onto opposite sides with respect to said carcass structure. Tyre for vehicle wheels according to claim 1 , wherein said structural element is an inner structuralelement. Tyre for vehicle wheels according to claim 3, wherein said inner structural element is selected fromthe group comprising tread underlayer, carcass structure, belt structure, bead structure, sidewalland underliner. Tyre for vehicle wheels according to any one of preceding claims, wherein said functionalizedlignin is obtained from sulfur-free lignin. Tyre for vehicle wheels according to any one of preceding

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claims, wherein said carbon black reinforcing filler (b) is present in the elastomeric material in anamount ranging from about 0.1 phr to about 90 phr, preferably from about 5 phr to about 70 phr. Front Page Drawing:

Assignee/Applicant: Pirelli Tyre S.p.A.,20126 Milano,IT,101433095

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Record 26/36 BR200113038A Processo para produzir um cabo para distribuição ou transmissãode energia elétrica de tensão elétrica média ou alta, cabo, e, método para aumentar a resistênciadielétrica de pelo menos um revestimento Inventor: ANNA GAIA DELL | SCELZA CRISTIANA | CASTELLANI LUCA | BAREGGI ALBERTO| ALBIZZATI ENRICO Abstract: "PROCESSO PARA PRODUZIR UM CABO PARA DISTRIBUIçãO OU TRANSMISSãO DEENERGIA ELéTRICA DE TENSãO ELéTRICA MéDIA OU ALTA, CABO, E, MéTODO PARAAUMENTAR A RESISTêNCIA DIELéTRICA DE PELO MENOS UM REVESTIMENTO". Apresente invenção refere-se a um processo para produzir um cabo, particularmente para adistribuição ou transmissão de energia elétrica de tensão elétrica média ou alta, o citado processocompreendendo a etapa de preparar pelo menos um revestimento de citado cabo a partir de ummaterial polimérico termoplástico orientado, o citado material termoplástico compreendendo umhomopolímero de propileno ou um copolímero de propileno e comonómero olefínico selecionado.Em detalhe, este processo compreende as etapas de alimentar pelo menos um condutor docitado cabo a uma máquina extrusora, extrusar o citado pelo menos um revestimento em umaposição radialmente externa ao citado pelo menos um condutor, orientar o citado pelo menos umrevestimento durante a citada etapa de extrusão. A presente invenção também se refere a umcabo, particularmente para a distribuição ou transmissão de energia elétrica de tensão elétricamédia ou alta, proporcionado com um revestimento de material polimérico termoplásticoorientado. Title: Processo para produzir um cabo para distribuição ou transmissão de energia elétrica detensão elétrica média ou alta, cabo, e, método para aumentar a resistência dielétrica de pelomenos um revestimento Title - DWPI: Production of cable for e.g. medium/high voltage electric power transmissioninvolves orientation of extruded insulating coatings onto conductors Publication Number: BR200113038A Priority Date: 2000-08-07 | 2000-08-11 | 2001-07-13 First Claim: Front Page Drawing:

Assignee/Applicant: PIRELLI E CAVI E SISTEMI S P A

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Record 27/36 WO2015166411A1 PROCESS FOR PRODUCING TYRES FOR VEHICLEWHEELS | PROCÉDÉ DE PRODUCTION DE PNEUS POUR ROUES DE VÉHICULE Inventor: BERENGUER, Albert | CASTELLANI, Luca | MICELI, Riccardo Abstract: A process is described for producing tyres for vehicle wheels comprising the covering of theexternal surface of an expandable chamber (9) for tyre vulcanisation and moulding apparatuseswith a substantially cross-linkable polysiloxane composition A, which composition contains at leastone cyclic polysiloxane as solvent, and the subsequent cross-linking of the composition executedat least three times. Also described are a process for treating an expandable chamber (9) as wellas the expandable chamber (9) for tyre vulcanisation and moulding apparatuses thus treated. L'invention concerne un procédé de production de pneus pour roues de véhicule comprenant lerevêtement de la surface externe d'une chambre expansible (9) pour des appareils devulcanisation et de moulage de pneus par une composition A de polysiloxane substantiellementréticulable, laquelle composition contient au moins un polysiloxane cyclique en tant que solvant, etla réticulation subséquente de la composition exécutée au moins trois fois. L'invention concerneégalement un procédé de traitement d'une chambre expansible (9) ainsi que la chambreexpansible (9) pour des appareils de vulcanisation et de moulage de pneus ainsi traitée. Title: PROCESS FOR PRODUCING TYRES FOR VEHICLE WHEELS | PROCÉDÉ DEPRODUCTION DE PNEUS POUR ROUES DE VÉHICULE Title - DWPI: Producing tires for vehicle wheels, comprises forming green tire on forming drum,arranging expandable vulcanization chamber by e.g. covering external surface of chamber withsubstantially crosslinkable polysiloxane composition, and shaping Publication Number: WO2015166411A1 Priority Date: 2014-04-30 First Claim: 1. Process for producing tyres for vehicle wheels comprising: a) forming, on a forming drum, agreen tyre (100); b) arranging an expandable vulcanisation chamber (9); c) shaping, moulding andvulcanising the green tyre (100),wherein arranging an expandable vulcanisation chamber (9) comprises: b1 ) covering the external surface (1 1 ) of said expandable vulcanisation chamber with asubstantially cross-linkable polysiloxane composition A comprising: A1 ) at least one reactive polysiloxane oil having OH groups, A2) at least one cross-linking agent comprising at least two functional groups capable of reactingwith the reactive polysiloxane oil A1 ), and A6) at least one cyclic polysiloxane as a solvent b2) cross-linking said substantially cross-linkable polysiloxane composition A on the expandablechamber; b3) repeating at least once the aforesaid operations b1 ) and b2) consecutively, before starting thevulcanisation of the first green tyre. Front Page Drawing:

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Assignee/Applicant: PIRELLI TYRE S.P.A.,IT

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Record 28/36 WO2015166412A1 PROCESS FOR PRODUCING TYRES PROVIDED WITHAUXILIARY COMPONENTS FOR VEHICLE WHEELS | PROCÉDÉ DE PRODUCTION DEPNEUS COMPORTANT DES COMPOSANTS AUXILIAIRES POUR LES ROUES DEVÉHICULES Inventor: BERENGUER, Albert | CASTELLANI, Luca | MICELI, Riccardo Abstract: A process is described for producing tyres provided with auxiliary components for vehicle wheelscomprising the covering of the external surface of an expandable chamber for tyre vulcanisationand moulding apparatuses with a first substantially cross-linkable polysiloxane composition A andthe covering of the radially inner surface of the impermeable elastomeric material layer of thegreen tyre with a second substantially non-cross-linkable polysiloxane composition B. Alsodescribed are an expandable chamber for tyre vulcanisation and moulding apparatuses, as well asa process for treating the expandable chamber. L'invention concerne un procédé de production de pneus comportant des composants auxiliairespour les roues de véhicules. Le procédé consiste à recouvrir la surface externe d'une chambreextensible pour dispositifs de moulage et de vulcanisation de pneus avec une premièrecomposition de polysiloxane sensiblement réticulable A, et à recouvrir la surface radialementinterne de la couche de matériau élastomère imperméable du pneu vert avec une secondecomposition de polysiloxane sensiblement non réticulable B. L'invention concerne également unechambre extensible pour dispositifs de moulage et de vulcanisation de pneus, ainsi qu'un procédépermettant de traiter la chambre extensible. Title: PROCESS FOR PRODUCING TYRES PROVIDED WITH AUXILIARY COMPONENTSFOR VEHICLE WHEELS | PROCÉDÉ DE PRODUCTION DE PNEUS COMPORTANT DESCOMPOSANTS AUXILIAIRES POUR LES ROUES DE VÉHICULES Title - DWPI: Publication Number: WO2015166412A1 Priority Date: 2014-04-30 First Claim: 1 . Process for producing tyres provided with auxiliary components for vehicle wheels, comprising:a) forming, on a forming drum, a green tyre comprising a carcass structure comprising at least onecarcass layer having opposite lateral edges associated with respective bead structures, a pair ofsidewalls laterally applied on opposite sides of said carcass structure, a layer of impermeableelastomeric material applied at a radially inner position with respect to said carcass structure, b) arranging an expandable vulcanisation chamber; c) shaping, moulding and vulcanising the green tyre in a manner so as to obtain a finished tyre; d) making an auxiliary component adhere on a first radially inner surface portion of the tyre; wherein arranging an expandable vulcanisation chamber comprises: b1 ) covering the external surface of said expandable vulcanisation chamber with a firstsubstantially cross-linkable polysiloxane composition A comprising A1 ) at least one reactivepolysiloxane oil having OH groups, A2) at least one cross-linking agent comprising at least twofunctional groups capable of reacting with the reactive polysiloxane oil A1 ) b2) cross-linking said first substantially cross-linkable polysiloxane composition A on theexpandable chamber; b3) repeating at least once the aforesaid operations b1 ) and b2), and wherein shaping, moulding and vulcanising the green tyre comprises:

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c1 ) selecting at least one green tyre every n green tyres, where n is an integer less than 60; c2) covering at least one second portion of the radially inner surface of said impermeableelastomeric material layer of said at least one selected green tyre with a second substantially non-cross-linkable polysiloxane composition B comprising B1 ) at least one non-reactive polysiloxaneoil, wherein said second portion on the green tyre corresponds with a portion on the finished tyresubstantially not superimposing said first portion. Front Page Drawing:

Assignee/Applicant: PIRELLI TYRE S.P.A.,IT

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Record 29/36 WO2011064655A3 PARTICULATE FILTER, CATALYTIC COMPOSITIONSUSEFUL FOR REGENERATING SAID FILTER AND PROCESSES FOR THEIR PREPARATION |FILTRE À PARTICULES, COMPOSITIONS CATALYTIQUES UTILISABLES EN VUE DE LARÉGÉNÉRATION DUDIT FILTRE ET LEURS PROCÉDÉS DE PRÉPARATION Inventor: ARIMONDI, Marco | CASTELLANI, Luca | KOPNIN, Evgeny | SIN XICOLA, Agusti Abstract: A particulate filter (1) is described comprising a filtering body (5) formed by a porous substrate andprovided with a plurality of gas channels (6', 6") defined by gas- permeable walls (7) of saidsubstrate, said gas-permeable walls (7) being coated with a catalytic composition comprising: a) ametallic phase having the formula: Ag 1-xPdx, wherein x is a number comprised between 0 and0.2; and b) a cerium oxide doped with at least one rare earth group metal having the formula: Ce1-

yRyO2-Y/2, wherein R is a rare earth group metal selected from Gd, Sm, Eu, La, and mixturesthereof and y is a' number comprised between 0.1 and 0.5. Catalytically active compositionsuseful for regenerating a filter (1) of this type, the use of these compositions as a catalytic activecoating of a filtering element of an exhaust gas emitted by an internal combustion engine (4), aswell as processes for preparing the filter (1) and compositions are also described. La présente invention concerne un filtre à particules (1) comprenant un corps assurant la filtration(5), constitué d'un substrat poreux et doté d'une pluralité de canaux dans lesquels s'écoulent lesgaz (6', 6''). Lesdits canaux sont délimités par les parois perméables aux gaz (7) dudit substrat,lesdites parois perméables aux gaz (7) étant revêtues d'une composition catalytique comprenanta) une phase métallique de formule : Ag 1-xPdx, où x est un chiffre compris entre 0 et 0,2 ; et b) unoxyde de cérium dopé au moyen d'au moins un métal du groupe des terres rares de formule : Ce1-

yRyO2-Y/2, où R est un métal du groupe des terres rares choisi parmi le Gd, le Sm, l'Eu, le La etdes mélanges de ceux-ci, y étant un chiffre compris entre 0,1 et 0,5. L'invention concerneégalement des compositions catalytiquement actives utilisables pour la régénération d'un filtre (1)de ce type, l'utilisation de ces compositions en tant que revêtement catalytiquement actif d'unélément filtrant les gaz d'échappement émis par un moteur à combustion interne (4), ainsi que desprocédés de préparation du filtre (1) et des compositions associées. Title: PARTICULATE FILTER, CATALYTIC COMPOSITIONS USEFUL FOR REGENERATINGSAID FILTER AND PROCESSES FOR THEIR PREPARATION | FILTRE À PARTICULES,COMPOSITIONS CATALYTIQUES UTILISABLES EN VUE DE LA RÉGÉNÉRATION DUDITFILTRE ET LEURS PROCÉDÉS DE PRÉPARATION Title - DWPI: Particulate filter, useful in post-treatment system to eliminate or minimize emissionof soot particles by diesel engine, comprises filtering body comprising gas channels defined bygas permeable walls of substrate Publication Number: WO2011064655A3 Priority Date: 2009-11-27 | 2009-12-18 First Claim: Front Page Drawing:

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Assignee/Applicant: PIRELLI & C. S.P.A.,IT | ARIMONDI Marco,IT | CASTELLANI Luca,IT |KOPNIN Evgeny,IT | SIN XICOLA Agusti,IT

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Record 30/36 WO2009056154A1 DIELECTRIC RESONATOR | RÉSONATEUR DIÉLECTRIQUE Inventor: CASTELLANI, Luca | FORMAGGIO, Virna | RICCI, Fabrizio Abstract: The present invention refers to a dielectric resonator comprising a dielectric material (4) includingdielectric ceramic composition comprising at least one surface treated dielectric filler and at leastone heterophase copolymer comprising a thermoplastic phase based on propylene and anelastomeric phase based on ethylene copolymerized with an alpha-olefin. Said dielectric resonatorshows good dielectric properties and is able to be easily assembled into a dielectric antennadevice. La présente invention concerne un résonateur diélectrique comprenant un matériau diélectrique(4) constitué d'une composition céramique diélectrique comportant au moins une matière deremplissage diélectrique traitée en surface et au moins un copolymère hétérophase comprenantune phase thermoplastique à base de propylène et une phase élastomère à base d'éthylènecopolymérisé au moyen d'une alpha-oléfine. Ledit résonateur diélectrique présente de bonnespropriétés diélectriques et peut être facilement monté dans un dispositif d'antenne diélectrique. Title: DIELECTRIC RESONATOR | RÉSONATEUR DIÉLECTRIQUE Title - DWPI: Dielectric resonator for dielectric antenna device has dielectric material includingceramic composition comprising heterophase copolymer having thermoplastic phase andelastomeric phase Publication Number: WO2009056154A1 Priority Date: 2007-10-30 First Claim: 1. A dielectric resonator comprising a dielectric material including dielectric ceramic compositioncomprising at least one surface treated dielectric filler and at least one heterophase copolymercomprising a thermoplastic phase based on propylene and an elastomeric phase based onethylene copolymerized with an -olefin. Front Page Drawing:

Assignee/Applicant: PIRELLI & C. S.P.A.,IT | TELECOM ITALIA S.P.A,IT | CASTELLANILuca,IT | FORMAGGIO Virna,IT | RICCI Fabrizio,IT

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Record 31/36 KR536616B1 ABLES WITH A HALOGEN-FREE RECYCLABLE COATINGCOMPRISING POLYPROPYLENE AND AN ETHYLENE COPOLYMER HAVING HIGHSTRUCTURAL UNIFORMITY Inventor: CASTELLANI, Luca | ReDonDo GeuRiJanTte EDuAReuDo | JaOPo AnToNiO |AlBiJjaTti EnRiKo Abstract: Title: ABLES WITH A HALOGEN-FREE RECYCLABLE COATING COMPRISINGPOLYPROPYLENE AND AN ETHYLENE COPOLYMER HAVING HIGH STRUCTURALUNIFORMITY Title - DWPI: More processable, expandable styrene polymer particles prepared by covering theparticles with an antistatic agent then vigorous mixing to heat their surface by mechanical friction Publication Number: KR536616B1 Priority Date: 1998-07-23 First Claim: Front Page Drawing:

Assignee/Applicant: PLRELLI CAVI E SISTEMI S.p.A.,IT

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Record 32/36 KR536615B1 CABLES WITH HALOGEN-FREE RECYCLABLE COATINGCOMPRISING POLYPROPYLENE AND ETHYLENE COPOLYMER HAVING HIGH ELASTICRECOVERY Inventor: CASTELLANI, Luca | ReDonDo GeuRiJanTte EDuAReuDo | JaOPo AnToNiO |AlBiJjaTti EnRiKo Abstract: Title: CABLES WITH HALOGEN-FREE RECYCLABLE COATING COMPRISINGPOLYPROPYLENE AND ETHYLENE COPOLYMER HAVING HIGH ELASTIC RECOVERY Title - DWPI: Cable with recyclable coating, used for power or data transmission comprising non-crosslinked coating material containing crystalline polypropylene and an elastomeric ethylenecopolymer with low tension set Publication Number: KR536615B1 Priority Date: 1997-07-23 First Claim: Front Page Drawing:

Assignee/Applicant: PLRELLI CAVI E SISTEMI S.p.A.,IT

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Record 33/36 KR552083B1 Low-smoke self-extinguishing cable and flame-retardant compositionused therein Inventor: CASTELLANI, Luca | ALBIZZATI, Enrico | ZAOPO, Antonio | TIRELLI, Diego |RERUZZOTTI, Franco | REDONDO GRIZANTE, Eduardo Abstract: From corresponding WO1999005688A1 Cable, in particular fow low-voltage electrical energy distribution or for telecommunications, havinglow-smoke self-extinguishing properties, comprising a conductor and a halogen-free flame-retardant coating wherein natural magnesium hydroxide is used as flame-retardant filler. Thiscoating comprises (a) a crystalline propylene homopolymer or copolymer; (b) a copolymer ofethylene with at least one alpha-olefin having from 3 to 12 carbon atoms, and optionally with adiene, said copolymer (b) being characterized by a composition distribution index, defined as theweight percentage of copolymer molecules having an alpha-olefin content within 50 % of theaverage total molar content of alpha-olefin, greater than 45 %; (c) natural magnesium hydroxide. From corresponding WO1999005688A1 L'invention concerne un câble autoextinguible à faible fumée, en particulier pour la distributiond'énergie électrique sous faible tension ou pour les télécommunications, qui comprend unconducteur et un revêtement retardateur de flamme dépourvu d'halogène dans lequel on utilise del'hydroxyde de magnésium naturel comme matière de charge à effet retardateur de flamme. Lerevêtement en question comprend (a) un homopolymère ou un copolymère de propylène cristallin;(b) un copolymère d'éthylène qui comporte au moins une alpha-oléfine ayant entre 3 et 12 atomesde carbone, et qui comporte éventuellement un diène; ledit copolymère (b) est caractérisé par unindice de distribution de composition supérieur à 45 %, cet indice étant défini comme lepourcentage pondéral des molécules de copolymère dont la teneur en alpha-oléfine est dans unemarge de 50 % par rapport à la teneur molaire moyenne totale en alpha-oléfine; (c) de l'hydroxydede magnésium naturel. Title: Low-smoke self-extinguishing cable and flame-retardant composition used therein Title - DWPI: Flame retardant coating composition for making cables self extinguishing useful forlow voltage electrical energy distribution and telecommunication cables with superior mechanicalproperties Publication Number: KR552083B1 Priority Date: 2000-01-22 First Claim: From corresponding WO1999005688A1 magnesium hydroxide thus obtained is claimed to be useful as a flame-retardant for polyolefin resins. In particular, the examples describe compositions withflame-retardant properties based on ethylene/vinyl acetate (EVA) and ethylene/ethyl acrylate(EEA) copolymers. Japanese patent application JP-03-231,944 (Kokai) describes polyolefin-basedcompositions having flameretardant properties and containing magnesium hydroxide with anaverage particle diameter of between 3 and 13 pm and the following particle size distribution: 1-20% by weight of particles with a diameter less than or equal to 1 pm; 55-98% by weight ofparticles with a diameter between 1 and 15 pm; 1-25% by weight of particles with a diameter

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between 15 and 50 pm. This particle size distribution is believed to afford higher flame resistance,which would be accompanied by good mechanical strength, flexibility and processability. Amagnesium hydroxide with these properties would be obtainable by suitable grinding of naturalbrucite, followed by sieving or addition of another material of predetermined particle size.According to the description given in the abovementioned patent application, this type ofmagnesium hydroxide would be useful as a flame-retardant filler for polyolefins such aspolyethylene, olefinic rubbers, polypropylene, polybutene and the like. Particular mention is madeof ultra-low-density polyethylene (ULDPE) having a density of 0.860-0.910 g/cm 3, obtainable bycopolymerization of ethylene with an alpha-olefin in the presence of a conventional Ziegler-Nattacatalyst based on titanium and/or vanadium compounds. Lastly, Japanese patent application JP-05-17692 (Kokai) describes polymer compositions havingflameretardant properties and containing natural magnesium hydroxide which has previously beenground and surface treated with a fatty acid or a fatty acid salt, or alternatively with a silane or atitanate acting as coupling agent. These compositions would be characterized by high resistanceto acid attacks. The subsequent Japanese patent application JP-07-161230 (Kokai) describescompositions similar to the above, pointing out that, in order to decrease the hygroscopicity ofmagnesium hydroxide, the latter must be surface-treated with the same products as mentionedabove, in amounts of between 0.5 and 5% by weight relative to the magnesium hydroxide weight.In both of the above-mentioned Japanese patent applications, polyolefins such as polyethylene,ethylene /propylene rubbers, acrylic rubbers and the like are cited as polymeric materials, andflame-retardant compositions based on ethylene/ethylacrylate (EAA) polymers are given asparticular examples. No information is provided regarding mechanical, elastic or processabilityproperties of the resulting mixtures. From the foregoing, it is clear that in the prior art considerable efforts have been made to improvethe properties of flame-retardant polymer compositions containing magnesium hydroxide bymodifying the properties of magnesium hydroxide itself, in terms of crystallinity, particle sizedistribution and/or surface properties. These modifications have been achieved either bydeveloping synthetic processes starting from soluble magnesium salts or by appropriatelymodifying and treating natural magnesium hydroxide. For the purposes of the present invention,with enhanced flame-retardant properties it is meant that a cable passes a test as defined bystandard CEI 332-1; with enhanced mechanical properties it is meant a high elongaticn at breakvalue and a relatively low modulus, which are capable of determining a cable flexibility which issuitable for use; in particular, it is meant that mechanical properties are essentially not lower thanthose of cables using compositions of known type, for example halogenated compositions. TheApplicant has now found that it is possible to produce self-extinguishing, halogen-free cablesproducing a low level of fumes and having high flame resistance and excellent mechanicalperformances by using natural magnesium hydroxide as flame-retardant filler and, as polymermatrix, a polymeric mixture comprising a crystalline propylene homopolymer or copolymer and acopolymer of ethylene with an alpha-olefin, and optionally with a diene, characterized by uniformdistribution of the alpha-olefin among the copolymer molecules. Therefore, according to a firstaspect, the present invention relates to a cable with self-extinguishing properties, comprising aconductor and a flame-retardant coating, characterized in that the said flame-retardant coatingcomprises: (a) a crystalline propylene homopolymer or copolymer; (b) a copolymer of ethylenewith at least one alphaolef in, and optionally with a diene, said copolymer (b) being characterizedby a composition distribution index greater than 45%, said index being defined as the weightpercentage of copolymer molecules having an alpha-olefin content within 50% of the average total

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molar content of alpha-olefin; (c) natural magnesium hydroxide in an amount such as to impartflame-retardant properties. In a second aspect, the present invention relates to a flame-retardant composition comprising: (a)a crystalline propylene homopolymer or copolymer; (b) a copolymer of ethylene with at least onealphaolefin, and optionally with a diene, said copolymer (b) being characterized by a compositiondistribution index greater than 45%, said index being defined as the weight percentage ofcopolymer molecules having an alpha-olefin content within 50% of the average total molar contentof alpha-olefin; (c) natural magnesium hydroxide in an amount such as to impart flame-retardantproperties. The composition distribution index provides an indication of the distribution of the alpha-olefinamong the copolymer molecules (the higher the value of this index, the more homogeneous thedistribution of the comonomer among the copolymer molecules), and can be determined byTemperature Rising Elution Fractionation, as described, for example, in patent US-5,008,204 or inWild et al. , J. Poly. Sci. Poly. Phys. Ed., Vol. 20, p. 441 (1982). Tn the Applicant's the composition view, distribution index is related to the ability of thecopolymers of ethylene with an alpha-olefin, and optionally with a diene, to incorporate anddisperse large amounts of the flame-retardant filler, thereby obtaining a mixture having excellentflame-resistance and, at the same time, good processability and improved mechanical properties.Given a certain ratio between flame-retardant filler and polymer matrix, it is important to determinethe minimum value of this index which is sufficient to obtain the desired combination of mechanicalproperties and processability. Moreover, the presence in the polymer mixture of a crystalline propylene homopolymer orcopolymer makes it possible to obtain a thermoplastic coating which has increasedthermocompression resistance even at the maximum operating temperatures, so as to pass thethermocompression test described in CEI standard 20-34/31. This test consists in subjecting the coating of a cable specimen to a predetermined compression ata predetermined temperature and for a predetermined time. At the end of the test, the flattening degree of the coating, expressed as percentage of the residualthickness relative to the initial thickness of the coating, is measured: the sample passes the test ifits residual thickness is greater than 50% of its initial thickness. In a further aspect, the presentinvention relates to a method for obtaining a cable having improved mechanical properties andincreased fire resistance, said method comprising the following steps: (1) preparing a polymermixture having flameretardant properties; (2) extruding said mixture on a conductor optionallyprecoated with an insulating layer, characterized in that step (1) comprises mixing apredetermined amount of natural magnesium hydroxide with a polymer mixture comprising: (a) acrystalline propylene homopolymer or copolymer, as a polymeric component capable of increasingthe thermocompression resistance of the flame-retardant coating; and: (b) a copolymer of ethylenewith at least one alphaolefin, and optionally with a diene, capable of dispersing natural magnesiumhydroxide, so as to improve processability of the mixture and enhance mechanical properties ofthe flame-retardant coating. The amount of natural magnesium hydroxide to be added is predetermined so as to obtain a cable

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which is capable of passing the fire-resistance test according to CEI standard 332-1. The amountof propylene homopolymer or copolymer (a) is such that the flame-retardant coating obtained afterextrusion has a value of thermocompression resistance, measured at 1000C according to CEIstandard 20-34/3-1, greater than 50%. The amount of copolymer (b) is such that the flame-retardant coating obtained after extrusion has an elongation at break, measured according to CEIstandard 20-34 5.1, of at least 100%, preferably of at least 150%, and a modulus at 20%,measured according to CEI standard 20-34 5.1, of less than 12 MPa, preferably less than 7 MPa. Figure 1 shows, in a schematic form, the crosssection of a low-voltage electrical cable of unipolartype according to one embodiment of the present invention, this cable comprising a conductor (1),an inner layer (2) acting as electrical insulation and an outer layer (3) acting as a protective sheathwith flameretardant properties, consisting of the composition according to the present invention. The term "low voltage" is understood generally to refer to a voltage of less than 2 kV, preferablyless than 1 kV. The inner layer (2) may consist of a haiogen-free, crosslinked or non-crosslinked polymercomposition with electrically insulating properties which is known in the art, selected, e.g., from:polyolefins (homopolymers or copolymers of different olefins), olefin/ethylenically unsaturatedester copolymers, polyesters, polyethers, polyether/polyester copolymers, and mixtures thereof. Examples of such polymers are: polyethylene (PE), in particular linear low density PE (LLDPE);polypropylene (PP) ; propylene/ethylene thermopl:astic copolymers; ethylene/propylene rubbers(EPR) or ethylene /propylene/diene rubbers(EPDM) ; natural rubbers; butyl rubbers;ethylene/vinylacetate (EVA) copolymers; ethylene/methylacrylate (EMA) copolymers;ethylene/ethylacrylate (EEA) copolymers; ethylene /butylacrylate (EBA) copolymers; ethylene/alphaolefin copolymers, and the like. It is also possible to use the same polymer base for the innerlayer (2) as well as for the outer layer (3), namely the mixture of (a) and (b) as defined above. Alternatively, a self-extinguishing cable according to the present invention may consist of aconductor coated directly with the flame-retardant composition described above, withoutinterposing other insulating layers. In this way, the flame-retardant coating also acts as electricalinsulator. A thin polymer layer acting as an anti-abrasive can then be externally added, optionallysupplemented with a suitable pigment to colour the cable for identification purposes. According to the present invention, with the term natural magnesium hydroxide it is meantmagnesium hydroxide obtained by grinding minerals based on magnesium hydroxide, such asbrucite and the like. Brucite is found in its pure form or,, more often, in combination with other minerals such as calcite,aragonite, talc or magnesite, often in stratified form between silicate deposits, for instance inserpentine asbestos, in chlorite or in schists. For the purposes of the present invention, brucite can be ground according to known techniques,under wet or dry conditions, preferably in the presence of grinding coadjuvants, for examplepolyglycols or the like. The specific surface of the ground product is generally between 5 and 20M2/g, preferably between 6 and 1,5 M2/g.

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The magnesium hydroxide thus obtained can then be classified, for example by sieving, to obtainan average particle diameter generally of between 1 and 15 pm, preferably between 1.5 and 5 pm,and a particle size distribution such that not more than 10% of the total number of particles have adiameter lower than 1.5 pm, and not more than 10% of the total number of particles have adiameter greater than 20 pm. Natural magnesium hydroxide generally contains various impurities derived from salts, oxidesand/or hydroxides of other metals such as Fe, Mn, Ca, Si, V, etc. Amount and nature of theimpurities can vary depending on the source of the starting mineral. The degree of purity isgenerally between 80 and 98% by weight. As regards water-soluble ionic-type impurities, theircontent can be determined indirectly by measuring electrical conductivity of an aqueous extractobtained by placing magnesium hydroxide in contact with a suitable amount of water for apredetermined period of time at a predetermined temperature. A more detailed description of thismeasurement, based on ISO method 787, is given hereinbelow. According to this method,electrical conductivity of the aqueous extract obtained from natural magnesium hydroxide isgenerally between 100 and 500 pS/cm, preferably between 120 and 350 pS/cm. The natural magnesium hydroxide according to the present invention can be used as such or inthe form of particles whose surface has been treated with saturated or unsaturated fatty acidscontaining from 8 to 24 carbon atoms, or metal salts thereof, such as, for example: oleic acid,palmitic acid, stearic acid, isostearic acid, lauric acid; magnesium or zinc stearate or oleate; andthe like. To increase compatibility with the polymer matrix, natural magnesium hydroxide can alsobe surfacetreated with suitable coupling agents, for example organic silanes or titanates such asvinyltriethoxysilane, vinyltriacetylsilane, tetraisopropyititanate, tetra-n-butyltitanate, and the like. Using Scanning Electron Microscopy (SEM), it has been observed that natural magnesiumhydroxide has a highly irregular granular morphology in terms both of its geometrical shape and ofits surface appearance. In contrast, the magnesium hydroxide obtained by precipitation consists offlattened hexagonal crystallites that are substantially uniform both in size and morphology. As regards the copolymers (b), they are generally characterized by a narrow molecular weightdistribution, with an index of molecular weight distribution (MWD) , defined as the ratio betweenthe weight-average molecular weight Mw and the number-average molecular weight Mn, Of lessthan 5, preferably between 1.5 and 3.5. The molecular weight distribution index can bedetermined, according to conventional methods, by Gel Permeation Chromatography (GPC). With alpha-olefin it is meant an olefin of formula CH2=CH-R, wherein R is a linear or branchedalkyl having from 1 to 10 carbon atoms. The alphaolefin can be selected, for example, frompropylene, 1-butene, 1 pentene, 4-methyl-l-pentene, 1-hexene, 1-octene, 1_ dodecene and thelike. Propylene, 1-hexene and 1-octene are particularly preferred. When the alpha-olefin is propylene, the copolymers (b) are also characterized by highregioregularity in the sequence of monomer units. In particular, these copolymers have a numberof-CH2-groups in-(CH2)n_ sequences, where n is an even integer, relative to the total number of-CH2-groups, generally lower than 5% by mole, preferably lower than 1% by mole. This quantitycan be determined according to known techniques by means of 3C-NMR analysis. When a diene comonomer is present, it generally has from 4 to 20 carbon atoms, and is preferably

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selected from: linear, conjugated or non-conjugated diolefins, for example 1,3-butadiene, 1,4-hexadiene or 1,6-octadiene; monocyclic or polycyclic dienes, for example 1,4cyclohexadiene,-ethyl idene-2-norbornene, 5-methylene-2norbornene, and the like. In general, for the purposes of the present invention, the desired mechanical andthermocompression resistance characteristics of the flame-retardant coating may be obtainedusing polymer mixtures comprising from 5 to 60% by weight, preferably from 10 to 40% by weight,of a crystalline propylene homopolymer or copolymer (a), and from 40 to 95% by weight,preferably from 60 and 90% by weight, of a copolymer (b), the percentages being referred to thetotal weight of the polymeric components (a) and (b) . Within the class of copolymers (b) as defined above, two main groups of products can bedistinguished. The first group (bl) consists of copolymers of ethylene with at least one C3-C12 alpha-olefin, andoptionally a diene, these copolymers having elastomeric properties and preferably characterizedby:-melting enthalpy lower than 35 J/g, preferably lower than 30 J/g;-intrinsic viscosity [ill generallygreater than 1.0 dl/g, preferably greater than 2. 0 dl/g (determined in tetralin at 135'C);-Mooneyviscosity ML(1+4) at 125"C (measured according to Standard ASTM D1646) generally greaterthan 10, preferably of from 20 to 90;-solubility in pentane at 2CC generally greater than 80% byweight;-tension set at 200% (measured at 2CC for 1 minute according to ASTM standard D 412)lower than 30%. Tension set provides a measure of the elastic recovery properties of the non-crosslinked material.This is determined by subjecting a sample of the tested material to a tensile force such as toobtain an elongation of 200% for a predetermined period. After removing the stress, thepermanent deformation of the sample, which is expressed as a percentage relative to its initialdimensions, is measured: the smaller this value, the better the elastic properties of the material. The copolymers belonging togroup (bl) generally have the followingcomposition: 35-90% by moleof ethylene; 10-65% by mole of alpha-olefin, preferably propylene; 0-10% by mole of a diene,preferably 1,4 hexadiene or 5-ethylidene-2-norbornene. When the alpha olefin is propylene, themonomer composition is preferably as follows: 55-80% by weight, preferably 65 75% by weight, ofethylene; 20-45% by weight, preferably 25-35% by weight, of propylene; 0-10% by weight,preferably 0-5% by weight, of a diene (preferably 5 ethylene-2-norbornene). When the alpha-olefinis propylene, the propylene units are in the form of triads generally in amounts of between 4 and50% by mole with respect to the total amount of propylene, and at least 70% of these triads haveisotactic structure, as shown by 13 C-NMR analysis. The second group (b2) consists of copolymers of ethylene with at least one C4-CI2 alpha-olefin,preferably 1-octene, and optionally a diene, preferably characterized by:-a density of between 0.86and 0.90 g/cm 3-a melting enthalpy of between 30 and 60 i/g;-Melt Flow Index (MFI), measuredaccording to ASTM standard D 1238/L, of between 0.1 and 30 g/10 min, preferably between 0.5and 5 g/10 min. The copolymers belonging to group (b2) generally have the following composition:75-97% by mole, preferably 90-95% by mole, of ethylene; 3-25% by mole, preferably 5-10% bymole, of alpha-olefin; 0-5% by mole, preferably 0-2% by mole, of a diene. The copolymers (b) can be obtained by copolymerization of ethylene with an alpha-olefin, and

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optionally with a diene, in the presence of a "singlesite" catalyst, for example a metallocenecatalyst, as described, e.g., in patent applications WO 93/19107 and EP-A-632,065 (for thecopolymers of group (bl)) or in patents US-5,246,783 and US-5,272,236 (for the copolymers ofgroup (b2) ) . The metallocenes used to polymerize the olefins are coordination complexes of atransition metal, usually of Group IV, in particular titanium, zirconium or hafnium, with twooptionally substituted cyclopentadienyl ligands, used in combination with a co-catalyst, forexample an alumoxane, preferably methylalumoxane, or a boron compound (see for exampleJ.M.S.-Rev. Macromol. Chem. Phys., C34(3), 439-514 (1994); J. Organometallic Chemistry, 479 (1994), 1-29, or patentsUS-5,272,236, US5,414,040 and US-5,229,478, or the above-mentioned patent applications WO93/19107 and EP-A-632065, and patents US5, 246, 783 and US-5, 272, 236) . Catalysts whichare suitable for obtaining the copolymers (b) according to the present invention are also thesocalled "Constrained Geometry Catalysts" described, for example, in patents EP-416,815 andEP-418,044. The crystalline propylene homopolymers or copolymers (a) generally have a melting enthalpygreater than 75 J/g, preferably greater than 85 J/g. They may be selected in particular from: (1)isotactic propylene homopolymers with an isotacticity index greater than 80, preferably greaterthan 90, even more preferably greater than 95; (2) propylene homopolymers obtainable by usingmetallocene catalysts, having a pentad irmimm content greater than 90% (determined by 13C-NMR analysis); (3) crystalline copolymers of propylene with ethylene and/or an alpha-olefin havingfrom 4 to 10 carbon atoms, with an overall content of ethylene and/or alpha-olefin lower than 10%by mole; (4) heterophasic propylene copolymers obtainable by polymerization in sequence ofpropylene and of mixtures of propylene with ethylene and/or an alpha-olefin having from 4 to 10carbon atoms, containing at least 70% by weight of polypropylene homopolymer or of crystallinepropylene /ethylene copolymer, with an isotacticity index greater than 80, the remainder consistingof an elastomeric ethylene /propylene copolymer with a propylene content of between 30 and 70%by weight; (5) crystalline propylene homopolymers or copolymers having syndiotactic structureobtainable by using metallocene catalysts. The amount of magnesium hydroxide which is suitable for imparting the desired flame-retardantproperties can vary within a wide range, generally between 10 and 90% by weight, preferablybetween 30 and 80% by weight, with respect to the total weight of the composition. Front Page Drawing:

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Assignee/Applicant: PLRELLI CAVI E SISTEMI S.p.A.,IT

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Record 34/36 IN244714B Inventor: Roba, Giacomo Stefano | Terruzzi, Lidia | Fogliani, Sabrina | Castellani, Luca | Resmini,Emiliano | Donetti, Raffaella | Grassi, Lisa Abstract: From corresponding WO2004031091A1 Optical fiber comprising: a) a glass portion; b) at least one protective coating layer disposed tosurround said glass portion; said protective coating layer having a modulus of elasticity valuebetween-40 °C and +60 °C comprised between 5 MPa and 600 MPa, preferably not higher than500 MPa, more preferably not higher than 450 MPa, much more preferably not higher than 300.Preferably, said protective coating layer is a single protective coating layer which is disposed incontact with said glass portion. From corresponding WO2004031091A1 L'invention concerne une fibre optique comprenant: a) une partie en verre; b) au moins unecouche de revêtement protecteur entourant la partie en verre; cette couche possédant une valeurde module d'élasticité, entre-40 °C et +60 °C, comprise entre 5 MPa et 600 MPa, plutôt inférieureà 500 MPa, ou encore mieux ne dépassant pas 450 MPa, mais de préférence inférieure à 300MPa. Cette couche de revêtement protecteur est constituée, de préférence, d'une couche uniqueen contact avec la partie en verre. From corresponding WO2004031091A1 L'invention concerne une fibre optique comprenant: a) une partie en verre; b) au moins unecouche de revêtement protecteur entourant la partie en verre; cette couche possédant une valeurde module d'élasticité, entre -40 DEG C et +60 DEG C, comprise entre 5 MPa et 600 MPa, plutôtinférieure à 500 MPa, ou encore mieux ne dépassant pas 450 MPa, mais de préférence inférieureà 300 MPa. Cette couche de revêtement protecteur est constituée, de préférence, d'une coucheunique en contact avec la partie en verre. Title: Title - DWPI: Optical fiber comprises glass portion and protective coating layer(s) disposed tosurround glass portion and having specific modulus of elasticity Publication Number: IN244714B Priority Date: 2005-03-10 First Claim: From corresponding WO2004031091A1 CLAIMS 1. Optical fiber comprising:-a glass portion;-at least one protective coating layer disposed tosurround said glass portion; said protective coating layer having a modulus of elasticity valuebetween-40°C and +6 0°C comprised between 5 MPa and 6 00 MPa. Front Page Drawing:

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Assignee/Applicant: Pirelli & CSPA,IT

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Record 35/36 IT1264964B1 RIVESTIMENTO PRIMARIO PER FIBRE OTTICHE FIBREOTTICHE COSI' RICOPERTE E PROCEDIMENTO PER PRODURLE Inventor: COCCHINI FRANCO | CASTELLANI LUCA Abstract: Title: RIVESTIMENTO PRIMARIO PER FIBRE OTTICHE FIBRE OTTICHE COSI' RICOPERTE EPROCEDIMENTO PER PRODURLE Title - DWPI: Primary cladding layer for optical fibres Publication Number: IT1264964B1 Priority Date: 1993-11-12 First Claim: Front Page Drawing:

Assignee/Applicant: FIBRE OTTICHE SUD F O S S P A | PIRELLI CAVI SPA

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Record 36/36 IT1993MI2411A1 RIVESTIMENTO PRIMARIO PER FIBRE OTTICHE FIBREOTTICHE COSI' RICOPERTE E PROCEDIMENTO PER PRODURLE Inventor: CASTELLANI LUCA | COCCHINI FRANCO Abstract: Title: RIVESTIMENTO PRIMARIO PER FIBRE OTTICHE FIBRE OTTICHE COSI' RICOPERTE EPROCEDIMENTO PER PRODURLE Title - DWPI: Publication Number: IT1993MI2411A1 Priority Date: 1993-11-12 First Claim: Front Page Drawing:

Assignee/Applicant: FIBRE OTTICHE SUD F O S S P A | PIRELLI CAVI S P A ORA PIRELLICAVI E SISTEMI S P

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