ZP- Dekote 1. Il>D'l'IrICA'IIotl OF TD SUBS1'.INCZ ...
Transcript of ZP- Dekote 1. Il>D'l'IrICA'IIotl OF TD SUBS1'.INCZ ...
1. Il>D'l'IrICA'IIotl OF TD SUBS1'.INCZ/PUPARHIOH AND OF TDCOMP.UIY/ma>DTAKIIIG
Pagel I 12 Pmdfec;t kllaffllll'
Product N81M DEKOTE
Other m•rw of Menttnc;a•lao
Synonyms None
Btcommeaded IIH pf lbe FbNDICII lad mlldclkaat AO uy
Recofflmended UN Industrial Ula Only
U... advlNd llplnst No Information available
Pet.Ms qf the NIPPlec o(lbe Mtetv "'" lhMt
SupphrName Eastwood Company
luppller Adclras 263 Shoemaker Rd
Pottstown PA 19464us
Suppller Phone Number Phone:1800-345-1178
,,....,,.., tp)ephQQe ,.,,,.., Company Enwrg811CJ Phone Nuntbllr 1-800-424-9300
2. HAZARDS IDENTIFICATION
ClnelflMUoo
Acute toxlc:lty- lnhalatton (Dust&'Mlsls) catagory4 Skin corrosionllrrttaUon Categofy 1 Sub-category A Selfoua eye dsr1lgeleye lntl8lion Cmegory 1 Flammable Hquldl Category4
EW#15246ZP- Dekote
1299914 Revlllon DIile 14-Dec-2015
GHs Label e1ementa. tncludlna pracautfoo•rv grtgments
Hazard Statements annful if inhaled
Danger
Causes severe skin bums and eye damage ombustlble Bquld
Pl'Kllutlonery Statements • Prevention Use only outdoors or In a well-ventilated area Do not breathe dust/fume/gaslml8t/Vapors/spray Wuh face, hands end any exposed skin thoroughly after handllng Wear protective gloves/protective clothing/eye protection/face protection Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Precautionary Statements - Response lmmedlalely call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid Instructions on this label)
Eyes
uld Odor Aromati
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, If present and auy to do. Continue rinsing Immediately cal a POISON CENTER or doctor/physician
Skin IF ON SKIN {or hair): RemoYafTake off Immediately al contaminated clothing. Rinse skin with watertshower Wash contaminated clothing before reuse
Inhalation IF INHALED: Remove victim to fresh air and keep at rest In a position comfor1able for breathing Call a POISON CENTER or doctor/physician If you feel unwell Immediately call a POISON CENTER or doctor/physician
Ingestion IF SWALLOWED: Rinse mouth. DO NOT Induce vomiting
Fire In case of fire: Use CO2. dry chemical, or foam for extinction
Precautionary Slat8ments • Stonge Store locked up Store In a well-ventilated place. Keep cool
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Prectiutlomlry Statements -Dl1posal Dispose of contenla/contalner to an approved waste disposal plant
Hmrde npt otblrwJH cllulflld (HNQC)
Not appllcable
Unknown Joxicttv 10 % of the mixture consists of lngredlent(s) of unknown toxicity
Oth,c lnformlllfon
May be harmful if swallowed May be harmful In contact with skin Harmful to aquattc life with long lasttng effects PROLONGED OR REPEATED CONTACT MAY ORY SKIN AND CAUSE IRRITATION
lntaractlon• with Other Chemtcela No lnfonnatlon available.
3. COMPOSmON/INFORMATION ON INGREDIENTS
themlcal name Benzvl alcohol �atic hydrocarbons, CS-11 Hvdmaen oeroxlde
1,3-0ioxolane
CASNo 100-51-6
70693,.06.0 IT22-84-1 846-06.()
w•ht-% Trade Secret 30-60 •
7-13 •
5-10 •
1-5 •
*The exact percentage (concenlratlon) of composition has bNn Withheld as a trade secret
0enm1 Advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first alder
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4. FIRST AID MEASURES
Immediate medical attention 11 required. Show this safety data sheet to the doctor In attendance.
Rinse Immediately with plenty of water, also under the eyelids. for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, If present and easy to do. Continue rinsing. Seek Immediate medical attention/advice.
Wash off immediately with soap and plenty of water while removing aH contaminated clothes and shoes. Seek immediate medical attention/advice.
Remove to fresh air. If breathing has stopped, give artificlal respiration. Get medical attention Immediately. Do not use mouth-to-mouth method if victim Ingested or Inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing Is difficult, (trained penionnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur.
Co NOT Induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center Immediately.
Ensure that medlcal personnel ara aware of the material(s) Involved, take precautions to
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protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-lo-mouth ruuacltaUon. Use personal protective equipment as required. We-. personal protective clothing (Me section 8). Remove all sources of Ignition.
Most important symptoms DOd ,u,ct1, both acute and delayed
Most Important Symptom• and Effectll
Burning sensation. Coughing and/ or wheezing. Dlfflculty In breathing.
lndlCltlQn ot any tmDJtdfat• mec:llcaJ attention end !PF•• treatment nfldld
Notes to Phy9Jclan Product Is a corroaive material Uae of gaatrfc lavage or ernesls Is contraindicated. Possible perforation of stomach or esophagus should be lnvaatigatad. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease In blood pressure may occur with moist rales, frothy sputum, and high pulse preuure.
5. FIRE-FIGHTING MEASURES
SuUabl• Extlnaulshlna Madll Use extinguishing measures that ate appropriate to local circumstances and tha surrounding environment. Dty chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
Un•ultabl• utlDAYllblOA media CAUTION: Use of water spray when fighting fire may be inafflclenl.
SpecHlc flvm!I ldllDP from tbt chemical The product causes bums of eyes, skin and mucous membranes. Thermal decomposition cat lead to release of lrritaUng gases end vapors. Keep product and empty container away from heat and sources of Ignition. In the event of flra, cool lanks with water spray.
Uniform Fl,. Cod•
Heumoua Combustion PrpductaCarbon oxides.
Euwllon Qm
Conoslve: Other-Liquid Toxic: Uqulcl Combustible Liquid: Ill-A
Sansltlvlty to Mechanical Impact No.
Senaltlvlty to Stade Discharge Yes.
protactlv, IPYIProtot IQd pracauUona tor flraftahtan AJ& In any fire, wear self-contained breathing apparatus pressute-demand, MSHA/NIOSH (approved or equivalent) and fuD protective gear.
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8. ACCIDENTAL RELEASE MEASURES
Peraonaf pm;autJoo1, protactlye equlpm-,t and ,rneraancv procedurn
Per80nal pr8C11Utlona
Other Information
Environmental pracautfpDf
Envlronmenbll prac:autlona
AltenUonl Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Avoid breathing vapors or mists. Avoid generatk>n of dust. See section 8 for more lnfonnation. Take precautionary measures against static discharges. Do not touch or walk through spilled material.
Refer to protective measures listed In Sections 7 and 8.
Refer to protective measures listed In Sections 7 and 8. Prevent further leakage or spillage If safe to do so. Should not be released Into the environment. Do not allow to enter Into SOll/sublail. Prevent product from entering drains.
Methods .,d mllterlal fgr containment end cf•DIDA up
Methods for containment
Methods for cleaning up
Precautfona tgr H(a rumdHng
twndllng
Prevent further leakage or spillage If safe to do so. Do not touch or walk through spilled material. Dike far ahead of Uquld spill for later disposal.
Pick up and transfer to property labeled containers. Take prac:autiona,y measures against static discharges. Dam up. Soak up with Inert absorbent material.
7. HANDLING AND STORAGE
Do not breathe dust/fume/gas/mist/vapors/spray.
condition• for afa atoraae, lncludfna any locompatlblHtfn
Storage
Incompatible Products
Keep containers tlghtiy closed In a dry, cool and well-ventlJaled place. Protect from moisture. Store locked up. Keep out of the reach of ehlldran. Stor8 away from other materials. Keep away from heat, sparks, name and other sources of ignition O.a., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Store In accon:fance wiltl the particular national regulations. Store In accordance with local regulation a.
Acids. Bases. Oxidizing agent.
8.EXPOSURE CONTROLS.IPERSONALPROTECTION
Control Ptmrnetaca
Eaposunt GuldellnN
Chemlcalname ACOIHTLV OSHA PEL NIOSHIDLH Hydrogen peroxide TWA· 1 ppm TWA 1 ppm IDLH:75ppm
n22.a4-1 TWA· 1.4 ninlm' TWA: 1 ftMI
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1ZIIH4
1,3-Dloxolane TWA:. 20 ppm 648-06-0
(vacaled) TWA: 1 ppm vacated TWA: 1A 2
Revfalon 0... 14-Dec-2015
TWA: 1.4 mglm3
A : Ametfcan Conlentnc:1t of Govemmtmtal lndustrt.l Hyplenlsls - T1nshold Umf VaAHP OSHA • CJc:cupalfoMJ Safety Md Ith Administration - Permlss1111e Exposure Umlfs NfOSH IDLH Immediately Dangerous lo Life or He.nh
Other Exposure Guidelines Vacated Hmlts revoked by the Court of Appeals decision In AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992)
Apprqprlattt toAlo,erlnq controls
Engineering MN.urea Showers Eyewash stations Ventilation systems
lndlY(duaf protection maasuras, such II Rtl'IPDII protective aauk>menl
l!ya'lace protection Face protection shield.
Skin •nd body protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves.
Respiratory protection Na protective equipment Is needed under nonnal use conditions. If exposure limits are exceeded or Irritation Is experienced, ventilation and evacuation may be required.
Hygiene lllusul'N Handle in accordance with good Industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat. drink or smoke when using this product. Take off contaminated clOlhlng and wash before reuse. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment. work area and clothing Is recommended. Wash hands before breaks and Immediately after handling the product. Take off contaminated clothing and wash before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
PhDICII and Ch,rnJcal Propartlu
Phy1lcal state Appe811111C8 Color
Property pH MelUng I freezing point Bollfng point I bolling range FJaahPolnt Evaporation Rate Rammllblllty (sold, gas) Flammeblllty LlmH In Air
Liquid Pink No lnfonnation available
v,, ....6 No data avaUabla 80 •c I 176 •F 93 CI 199 F No data available Na data available
Upper fllllnmeblHty llmlt No data available Lower flam!Mblllty limit No data available
Vapor preaure No data avaUable Vmpor daMlty Na data available Spectflc Gravity 1.05 W•ter Solublllty Miscible in water Solublllty In other solvents No data available Partition coefficient: n-octanolfwat.rNa data available
®
Odor Odor Tlueshold
Remarks Method Nona known None known None known None known None known None known
None known None known None known None known None known None known
Aromatic No lnformatlOn available
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AutolgnHlon temperature O.CompoeHlon temperature Klnemmlc vi.coatty Dvn•mlc viscosity Exploalve prof*IIN Oxidizing properties
Other: Information
Softening Paint voe Content (%) Particle Size Particle Size Dfstrl:,utlon
Btoc;tfylty
No data avallable.
Chemlclf ... blHty
No data available No dala available No data available 20000 No data available No dllll available
No data available No data available No data available
None known None known None known None known
10. STABILITY AND REACTIVITY
Stable under recommended storage conditions. PoulbflsY at tt111rdout Reaction• None under nonnal pn:,cesslng. Huarcloua Potymartzatton Hazardous polymerization does not occur.
CondlHoo, to avoid Exposure to air or moisture over prolonged periods. Excessive heat. Heat, flames and sparks. Incompatible matarlala Acid1. Bases. Oxidizing agent. Hazardoya pacompos1t1on Products Carbon oxides.
:11. 'ltOXI.COLOGICAL INFORMATION
lnfonnaUon on IHgtlv mutn pt pposura
Product Information
Inhalation
Eyeconlact
Skin contact
Ingestion
Specfflc test data for the substance or mixture Is not available. Corrosive by Inhalation. (based on components). Inhalation of corrosive fumes/gun may cause coughing, choking, headache, dizziness, and weakness for several hours. Pulmonary edema may occur with tlghtn8118 In the chest, shortness of breath, bluish skin, decreased blood pressure, and Increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal. May cause Irritation of respiratory tract. Harmful by Inhalation.
Specific teat data for the substance or mixture Is not available. Causes bums. (based on components). Com,si� to the eyes and may cause severe damage Including blindness. CaUHI serious eye damage. May cause lrreverslble damage to eyes.
Specific test data for the substance or mixture la not available. Corrosive. (based on components). Cau1&1 burns.
Specific lest data for the substance or mixture Is not available. Causes bums. (baled on components). Ingestion CIUMS bums of the upper digestive and respiratory !rads. May cause severe burning pain In the mouth and stomach with vomiting and diarrhea of dark blood. Blood presaure may decrease. Brownish or yellowi1h stains may be seen around the
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Component Information
Chemlcal Mme !Senzyt alcohol 100.51..e ·1-·---·· peroxide 7722-84-1
h ,3-Dlmolllne
mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung damage If swaHowed. May be fatal If swallowed and enters airways. Ingestion may cause Irritation to mucous membranes. Ingestion may cause gastrointestinal Irritation, nausea, vomiting and dlarmea.
Onl LOSO o.m.lLDIO Inhalation LC&O
• 1230 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) =8.8,ngA. (Rat)4h
= 1518 mg/kg (Rat) "' 2000 mg/kg ( Rabbit ) • 4060 •2glm' (RM)4hmnJlm ( RIil )
•3glkg (Rat) = 15 glkg ( Rat ) • 8480 �g ( • 20850 ,ng(rn' ( Ral ) 4 h Rabbk)
lnformatton on tox1cp1oa1ca1 effects
Symptom a Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
PwY!d •od hnmtdJIII @fflN:ts H wett II chronic effects from short lod Jonstterm PPPM!
Sensitization No Information available.
No lnfonnatlon available. Mutagantc Effecta
Cerclnog9111c1ty The table below Indicates whether each agency has listed any Ingredient as a carcinogen.
ACGIH IARC Group3
ACGfH (American Conference of Governmental tndustrls/ Hygl11t1tsts) A3 • Animal carcinogen /ARC (lntematlontll Agency for Raarch on Cllncer)GttH(O 3 • Not Cllml6ele u ,o c.rr:/nogenlclt In Humans
Reproductive toxicity
STOT - single exposure
STOT- rap...S exposure
No Information available.
No Information available.
No Information available.
OSHA
Chronic Toxicity No known effect based on lnfonnatlon auppfted. Chronic exposure to corrosive fumes/gases 11111y cause erosion of the teeth followed by jaw necrosis. Bronchial Irritation with chronic cough and frequent attacks of pneumonia ant common. Gastrointestinal disturbances may also be seen. Carcinogenic potential la unknown.
Target Organ Effects
Aspiration Huard
Respiratory system. Eya. Skin. Gastrointestinal tract (GI).
No lnfonnallon available.
Nurwtc:,1 ffllllYl'M pt toxicity Product lo(ormatlon
The following fflu• •re calculated bned on ch!lpter 3.1 of the GHS document
ATEmlx (oral} 2,600.00 mglkg ATEmlx (dermll} 5,000.00 mg/kg (ATE) ATEmlx (Inhalation-gas}
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Rev11lon 0.. 14-Dec-2015
1211114·
64,286.00 ppm (4 hr) A TEmlx (lnhalatlon-dustlmltt) 3.00 mg/I ATEmlx (lnhalmtlon-vapar) 157.00 ATEmix
12. ECOLOGICAL INFORMATION
EcotoxJctJV Harmful to aquauc life with long lasting effects.
Chamlal nmne Toxicity lo AJpe
Benzyl alcohol 3h EC50: = 35 mglL 100.51-8 (Anabaena varfabls)
Hydros,en peroxide 72h EC50: = 2.5 mglL n22-M-1 (Chlotella wig.ts)
PmllltwJCI IQd DaaradeblHty No lnfonnation available.
B1cJtccumu1a11on
Other adverse tfflctl No Information avaHable.
®
Benzyl alcohol 100.51�
Toxicity to Fish
96h LC50: = 10 mg/I. (Lepomls macrodllrus) 9811
LC50: a 4150 mglL (P . DrDmt1181)
96h LC50: 10.0·32.0mgll (Onc:orhynchus mylclss) 96h
LCSO: 18 • 58 mglL (lepamls rnacrodllrue) 98h
LC50: = 16.4 mg/I. IPlmeohales llfflmlllasl
Toxldtyto--·
'"·""
EC50 • 50 mgll 5 min EC50., 63.7 mglL 15 min EC50 • 63 7 rngll. 5 min
EC50 = 71 4 mnlL 30 min
Log Pow 1.1
.().37
Dlphnltl lllgna (Water Flea)
48h EC50. = 23 mglL
4811 EC50. 18 • 32 mgll.24' EC50: = 7.7 mglL
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Waste t[Htrnent methods
Contaminated Packaging
13. DISPOSAL CONSIDERATIONS
This material, as supplied, Is not a hazardous waste according to Federal regulations (40 CFR 261 ). Thia material could become a hazardous waste If It Is mixed with or othelwlse comes In contact with a hazardous waste, If chemical additions are made to this material, or If the materlal Is processed or otherwtse altered. eonsutt 40 CFR 261 to detennlne whether the altered material Is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Dispose of contents/containers In accordance wllh local regulations.
This product contains one _or mont 11ubatancaa that are listed with the State of calfomla as a hazardous waste.
Hydn,gen peroxide 7722-84-1
DOT Proper Shipping Name Huard Clan
Proper Shipping Name Huard Clan
NQGIINO Huard Clan
tnbtmational Inventories
TSCA OSL
14. TRANSPORT INFORMATION
NOT REGULATED NON REGULATED NIA
Not regulated
Not regulated
Not regulated
Not regulated NON REGULATED NIA
Not regulated NIA
Not regulated
Not regulated
Not regulated
15.REGULATORYINFORMATION
Complies All components are listed either on the DSl or NOSL.
TSCA - United Stales Toxic Substancel Conlral Ad Sedian B(b) lnventa,yDSLINDSL - Canlldlan Dom8111c Subauncu U111Non-Domeallc Substances List
®
Toxic Corrollve lgnllable Reactive
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1211914
US Federal Regulation•
SARA313 Section 313 of TtUe Ill of the Superfund Amandmenls and Reauthorization Act. of 1986 (SARA). This produc;t does not contain any chemicals which are subject to the reporting requirements of the Act and Trtle 40 of the Code of Federal Regulations, Part 372
SARA 3111312 Heum CatNorltf Acute Health Huard Chronic Health HIIIIIJ'd FlraHazard Sudd• ......_ of preuure hazard R•Cllvlt Hazard
CWA CCIHo Water Act)
Yes No
Yes No No
This product contains the fallowing substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Ct.mlaal nente CWA • Reparuble CWA • Tmlc PollutMla CWA • Priority Pollut8nla CWA·Hasdou9
Ou•ntlllM SUbNncN
Hydrogen peroxide X X X X 7722-84-1
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response CompensaUon and Llablllty Act (CERCLA) (40 CFR 302)
I --
H)ldrogen peroxide n22-M-1
US State Regulations
catHomJa Prppo1Dlo0 esThis product does not contain any Proposition 65 chemlcala.
u.s. State Bight-to-Know Rnulatlana
c11emic.11111me NewJ-
Be�afcohol 100.51-6
Hydrogen peroxide X
7722-84-1
1,3-Dloxolane X
646-06-0
International Regulation•
Alllmlll
'-xlco • Occupational Exposure Um/ls. CBlr:lnogens
Canada WHMIS Hazard Clan
®
RO
MuAchUHtls PennsYlnnl8 Rhode llland flllnola X X
X X X
X X
A3
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Not determined
NFPA
HMIS
Prepared By
Revision Date Revision Note
Disclaimer
Revlllon DIie 14-Dec-2015
16. OTHER INFORMATION
Health Hazards 3 FlammablAty 2
Health Hazards 3 AammabUlty 2
Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-650114-Dec-2015No Information avaHable
ln1tablllty O Phyalcal and Chemical Hazards
Physical Hazard o Personal Protection X
The Information provided In this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of Its publication. The Information given Is designed only as a guidance for safe handing, use, processing, storage, transportation, disposal and release and Is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or In any process, unless specified in the text
End of Safety Data Sheet
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